Clarify the role of Nb alloying on passive film and corrosion behavior of CoCrFeMnNi high entropy alloy fabricated by laser powder bed fusion

被引:28
|
作者
Zhang, Zhen [1 ,2 ]
Li, Xiaofeng [1 ]
Yi, Hong [1 ]
Xie, Huiqi [1 ]
Zhao, Zhanyong [1 ]
Bai, Peikang [1 ,3 ]
机构
[1] North Univ China, Sch Mat Sci & Engn, Shanxi Key Lab Controlled Met Solidificat & Precis, Taiyuan 030051, Peoples R China
[2] Taiyuan Iron & Steel Grp Co Ltd, Tech Ctr, Taiyuan 030003, Peoples R China
[3] Taiyuan Univ Sci & Technol, Taiyuan 030024, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
Alloy; Passive films; Pitting corrosion; XPS; MICROSTRUCTURE;
D O I
10.1016/j.corsci.2023.111510
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Effect of Nb alloying on passive film and corrosion behavior of laser powder bed fused CoCrFeMnNi high entropy alloy (HEA) was studied by microstructure analysis, electrochemical analysis and X-ray photoelectron spectroscopy. Nb alloying refined the grain size, promoted the Laves phase precipitation, and changed the inclusion type of the HEA. The improved corrosion resistance evidenced by increased pitting potential and polarization resistance was achieved by Nb alloying. Nb addition decreased the donor and acceptor density of the passive film, and altered its composition. The relationship of "microstructure-passive film-corrosion property" is discussed to illustrate corrosion enhancement mechanism of Nb alloying.
引用
收藏
页数:15
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