Effect of water-washing pretreatment on the enhancement of tetracycline adsorption by biogas residue biochar

Biochar preparation was a feasible strategy for realizing the reduction, harmlessness, and resource utilization of biogas residue (BR) simultaneously. How to enhance the adsorption performance of biogas residue biochar through simple, friendly, and effective way still needs to be investigated. In this study, water-washing pretreatment of BR was adopted before biochar preparation (BRBC-W), and pristine biochar (BRBC) was also produced to serve as control. The adsorption behavior and possible adsorption mechanisms of tetracycline (TC) onto biochars were comprehensively studied. The results showed that water-washing pretreatment could increase the surface area and mesoporous volume of biochar from 358.63 to 391.98 cm(3).g(-1), and 0.459 to 0.488 cm(3).g(-1), respectively. More graphitic structure was observed in BRBC-W. In addition, the surface morphology, element content, minerals composition, and surface functional groups also changed in biochar after water-washing pretreatment. The pseudo-second-order and Redlich-Peterson models better descried the adsorption behavior of TC on BCRBC-W. The maximum adsorption capacity of BRBC and BRBC-W for TC based on Langmuir isotherm was 224.93 and 306.94 mg.g(-1), respectively. The adsorption affinity of BRBC-W toward TC was greater than that of BRBC. BRBC and BRBC-W can effectively remove TC in water within a wide pH range and under the interference of co-existing ions. The adsorption mechanism of TC onto BRBC and BRBC-W included ore filling, pi-pi interaction, and hydrogen bonding. The enhancement of TC on BRBC-W by water-washing pretreatment was attributable to the strengthening of pore diffusion and pi-pi interaction. Therefore, water-washing pretreatment effectively enhanced the adsorption performance of BRB, and BRBC-W was an effective eco-friendly adsorbent for the removal of TC from aquatic environment.