Light Fe isotopes in arc magmas from cold subduction zones: Implications for serpentinite-derived fluids oxidized the sub-arc mantle

Arc basalts typically have higher Fe3+/IFe ratios but lighter Fe isotopic compositions than mid-ocean ridge basalts (MORB); however, the reasons for these differences are unclear. Here, we report new Fe iso-tope data for fresh lavas from the Mariana subduction zone, along with available Fe-B-Sr-Nd isotope and B/Nb ratio data for global arc basalts, to constrain the role of serpentinite dehydration in sub-arc mantle oxidation. The basaltic lavas from the Mariana Arc, like other arc basalts from cold subduction zones in the west Pacific, have lighter Fe isotope compositions (856Fe = 0.02 +/- 0.02%x; 1SD; n = 9) than the MORB-like 856Fe values of the middle Mariana Trough basalts (856Fe = 0.09 +/- 0.02%x; 1SD; n = 8). Notably, the significant negative correlations between the 856Fe values and the proxy for the addition of serpentinite-derived fluids (i.e., B isotopes and B/Nb ratios) indicate that the serpentinite-derived fluid contribution is a first-order control on the across-arc Fe isotope variations. Dehydration of subducted slab serpentinites or dragged-down forearc serpentinites at sub-arc depths can release isotopically light Fe fluids in the form of Fe2+-SOxcomplexes. Sulfate-rich fluids containing adequate Fe to metasomatize the sub-arc mantle can cause light Fe isotope compositions and high Fe3+/IFe ratios in arc basalts. Alternatively, the low 856Fe values and high Fe3+/IFe ratios of arc magmas may be generated by direct melting of the melange, which includes dragged-down sulfate-rich forearc serpentinites. Comparatively, serpentinite-derived components are absent at back-arc depths because of the earlier breakdown of serpentine minerals. Accordingly, the back-arc basin basalts exhibit MORB-like 856Fe-811B values and B/Nb-Fe3+/IFe ratios. Therefore, the across-arc Fe isotope variations and the decoupling of Fe3+/IFe and 856Fe in global arc magmas can be explained by the different contributions of subducted serpentinites.(c) 2022 Elsevier Ltd. All rights reserved.