Visible-Light-Induced Decarboxylative Aminosulfonylation of (Hetero)aryl Carboxylic Oxime Esters

被引：6
|
作者：
Zhuang, Zhen [1 ,2 ]
Sun, Yuting [1 ,2 ]
Zhong, Yuanchen [1 ]
He, Qian [1 ]
Zhang, Xiaofei [1 ]
Yang, Chunhao [1 ,2 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Mat Med, Dept Med Chem, State Key Lab Drug Res, Shanghai 201203, Peoples R China
[2] Univ Chinese Acad Sci, Sch Med, Beijing 100049, Peoples R China
来源：
ORGANIC LETTERS | 2024年 / 26卷 / 03期
关键词：
ALKENES;
D O I：
10.1021/acs.orglett.3c04142
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sulfonamides are important structures in pharmaceuticals, agrochemicals, and organocatalysts, yet the rapid and benign synthesis of these compounds is still a great challenge. Herein we report a photoinduced method for synthesizing sulfonamides from (hetero)aryl carboxylic acid oxime esters. This reaction proceeds via one-pot cascade radical-radical cross-coupling by energy-transfer-mediated photocatalysis. A wide substrate scope including (hetero)aryl substrates and late-stage modification of pharmaceutical molecular entities reveal its generality.
引用
收藏
页码：713 / 718
页数：6
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