Electrochemical cycloaddition of hydrazones with cyanamide for the synthesis of substituted 5-amine-1,2,4-triazoles

被引：8

作者：

Yang, Minghua ^{[1
]}

Jiang, Rui ^{[2
]}

Mu, Yangxiu ^{[2
]}

Hong, Yu ^{[2
]}

Wan, Yaya ^{[2
]}

Hou, Jing ^{[2
]}

Tang, Dong ^{[1
,2
]}

机构：

[1] Quzhou Coll Technol, Dept Chem & Mat Engn, 18 Jiangyuan Rd, Quzhou 324002, Zhejiang, Peoples R China

[2] Ningxia Acad Agr & Forestry Sci, Inst Agr Resources & Environm, Yinchuan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 16期

关键词：

T-BUOI; ACCESS; ANNULATION;

D O I：

10.1039/d2cc06277a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An eco-friendly and efficient electrochemical method for the synthesis of 5-amine-1,2,4-triazole derivatives has been developed by employing hydrazones or in situ generation of hydrazones with cyanamide using KI as the catalyst and electrolyte. This strategy could be smoothly conducted with simple reaction conditions at room temperature without the addition of a chemical oxidant in an undivided cell, and cyanamide has been proven to be of great value in electrosynthesis.

引用

页码：2303 / 2306

页数：4

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