High-Branched Organosilicon Epoxy Resin with Low Viscosity, Excellent Toughness, Hydrophobicity, and Dielectric Property

被引:4
|
作者
Yu, Min [1 ]
Chen, Zeyuan [1 ]
Li, Jie [1 ]
Tan, Jihuai [1 ]
Zhu, Xinbao [1 ,2 ]
机构
[1] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Coinnovat Ctr Efficient Proc & Utilizat Fo, Nanjing 210037, Peoples R China
[2] Anhui Engn Res Ctr Epoxy Resin & Addit, Huangshan 245900, Peoples R China
来源
MOLECULES | 2023年 / 28卷 / 06期
基金
中国国家自然科学基金;
关键词
silicone resins; viscosity reduction; toughening; hydrophobicity; dielectric properties; FLAME-RETARDANT;
D O I
10.3390/molecules28062826
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Rapidly developing technology places higher demands on materials, thus the simultaneous improvement of materials' multiple properties is a hot research topic. In this work, a high-branched silicone epoxy resin (QSiE) was synthesized and applied to the curing system of bisphenol A epoxy resin (DGEBA) for modification investigations. When 6 wt% QSiE was added to the system, the viscosity dropped by 51.8%. The mechanical property testing results indicated that QSiE could significantly enhance the material's toughness while preserving good rigidity. The impact strength was enhanced by 1.31 times when 6wt% of QSiE was introduced. Additionally, the silicon skeleton in QSiE has low surface energy and low polarizability, which could endow the material with good hydrophobic and dielectric properties. This work provided a new idea for the preparation of high-performance epoxy resin additives, and provided a broad prospect for cutting-edge applications of epoxy resins.
引用
收藏
页数:12
相关论文
共 50 条
  • [1] Epoxy/benzoxazinylPOSSnanocomposite resin with low dielectric constant and excellent thermal stability
    Li, Xiaodan
    Feng, Jiacheng
    Zhang, Shuai
    Tang, Ying
    Hu, Xinyu
    Liu, Xiaoping
    Liu, Xiaoqing
    JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (08)
  • [2] Resveratrol-Derived Liquid Crystal Epoxy Resin with Low-Dielectric Properties and Excellent Mechanical Strength and Toughness
    Yang, Hui
    Yuan, Guoming
    Jiao, Enxiang
    Wang, Kunxin
    Diao, Wenjie
    Li, Zhao
    Liu, Zhijun
    Wu, Kun
    Shi, Jun
    ACS APPLIED POLYMER MATERIALS, 2024, 6 (02) : 1116 - 1128
  • [3] Mechanical Properties and Fracture Toughness of Epoxy Resin Improved by Low-viscosity Hyperbranched Epoxy
    Zhang, Zhongwei
    Wang, Xiaolong
    Hu, Xiaoguang
    Xu, Ting
    Lin, Yanyan
    Tan, Yefa
    PROCEEDINGS OF THE 5TH INTERNATIONAL CONFERENCE ON ADVANCED DESIGN AND MANUFACTURING ENGINEERING, 2015, 39 : 1662 - 1666
  • [4] High toughness, thermal resistance and excellent dielectric properties phenolic epoxy vinyl ester resin modified by hyperbranched polyimide
    Gao, Feng
    Zhang, Xianrui
    Weng, Ling
    Cheng, Yujun
    Shi, Jiahao
    PIGMENT & RESIN TECHNOLOGY, 2022, 51 (04) : 441 - 448
  • [5] Composition design and property investigation of bismaleimide by branched crosslinking structure with low dielectric permittivity and high toughness
    Shi, Jiahao
    Wang, Xuan
    Gao, Yuanjie
    Zhang, Xiaorui
    Weng, Ling
    Sun, Xue
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2024, 35 (08)
  • [6] Low dielectric constant and high toughness epoxy resin based on hyperbranched polyester grafted by flexible chain modified
    Zilong Wang
    Xiaorui Zhang
    Ling Weng
    Lizhu Liu
    Journal of Materials Science: Materials in Electronics, 2019, 30 : 5936 - 5946
  • [7] Low dielectric constant and high toughness epoxy resin based on hyperbranched polyester grafted by flexible chain modified
    Wang, Zilong
    Zhang, Xiaorui
    Weng, Ling
    Liu, Lizhu
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (06) : 5936 - 5946
  • [8] Improving epoxy resin fracture toughness through biobased cashew nutshell liquid resin for high viscosity applications
    Maiorana, Anthony
    Ren, Liyun
    Lo Re, Giada
    Spinella, Stephen
    Ryu, Chang
    Dubois, Philippe
    Gross, Richard
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [9] A novel high-performance composite material with low dielectric constant and excellent hydrophobicity
    Zhu, Chuanren
    Zhang, Tong
    Su, Qing
    Wei, Zhimei
    Wang, Xiaojun
    Long, Shengru
    Zhang, Gang
    Yang, Jie
    JOURNAL OF MATERIALS SCIENCE, 2024, 59 (23) : 10248 - 10263
  • [10] Preparation of high performance foams with excellent dielectric property based on toughened bismaleimide resin
    Xie, Xiaoqin
    Gu, Aijuan
    Liu, Ping
    Liang, Guozheng
    Yuan, Li
    POLYMERS FOR ADVANCED TECHNOLOGIES, 2011, 22 (12) : 1731 - 1737