Cyanido-bridged FeII-NbIV spin-crossover complex with FeII-crosslinking ligands possessing disulfide bonds

被引：0
|
作者：
Kanno, Takefumi [1 ]
Nakabayashi, Koji [1 ]
Imoto, Kenta [1 ]
Tanaka, Yoshinori [1 ]
Ohkoshi, Shin-ichi [1 ]
机构：
[1] Univ Tokyo, Sch Sci, Dept Chem, 7-3-1 Hongo,Bunkyo Ku, Tokyo 1130033, Japan
来源：
INORGANICA CHIMICA ACTA | 2024年 / 559卷
关键词：
Spin crossover; Cyanido-bridged metal assembly; Coordination network; Slichter-Drickamer model; WIDE THERMAL HYSTERESIS; PRUSSIAN BLUE ANALOG; ELECTRON-TRANSFER; ROOM-TEMPERATURE; COORDINATION POLYMERS; LIGHT; TRANSITION; BEHAVIOR; 2D; LUMINESCENCE;
D O I：
10.1016/j.ica.2023.121769
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cyanido-bridged Fe-II-Nb-IV spin-crossover complex, [Fe-II(dpds)(2)](2)[Nb-IV(CN)(8)]<middle dot>6H(2)O (dpds = 4,4 '-dipyridyldisulfide), is synthesized with a three-dimensional coordination network. The network has cyanido bridges to connect the Fe-II and Nb-IV sites and dpds as an additional ligand to crosslink the Fe-II sites. [Fe-II(dpds)(2)](2)[Nb-IV(CN)(8)]<middle dot>6H(2)O exhibits a gradual and incomplete spin crossover in which 22% of the high-spin Fe-II sites change to low-spin Fe-II sites as the temperature decreases. The calculation indicates that the spin transition occurs sparsely, rather than forming low spin site domains.
引用
收藏
页数：8
相关论文
共 27 条
  • [1] Second harmonic generation on chiral cyanido-bridged FeII-NbIV spin-crossover complexes
    Kawabata, Shintaro
    Nakabayashi, Koji
    Imoto, Kenta
    Klimke, Stephen
    Renz, Franz
    Ohkoshi, Shin-ichi
    DALTON TRANSACTIONS, 2021, 50 (24) : 8524 - 8532
  • [2] Spin crossover phenomenon in a three-dimensional cyanido-bridged FeII-MoIV assembly
    Kawabata, Shintaro
    Nakabayashi, Koji
    Imoto, Kenta
    Ohkoshi, Shin-ichi
    JOURNAL OF APPLIED PHYSICS, 2021, 129 (10)
  • [3] Cyanido-Bridged FeII-MI Dimetallic Hofmann-Like Spin-Crossover Coordination Polymers Based on 2,6-Naphthyridine
    Pineiro-Lopez, Lucia
    Javier Valverde-Munoz, Francisco
    Seredyuk, Maksym
    Bartual-Murgui, Carlos
    Carmen Munoz, M.
    Antonio Real, Jose
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (3-4) : 289 - 296
  • [4] An FeII Spin-Crossover Complex Becomes Increasingly Cooperative with Ageing
    Craig, Gavin A.
    Sanchez Costa, Jose
    Roubeau, Olivier
    Teat, Simon J.
    Aromi, Guillem
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, (5-6) : 745 - 752
  • [5] Solvent Dependent Spin-Crossover and Photomagnetic Properties in an Imidazolylimine FeII Complex
    Archer, Rosanna J.
    Scott, Hayley S.
    Polson, Matthew I. J.
    Mathoniere, Corine
    Rouzieres, Mathieu
    Clerac, Rodolphe
    Kruger, Paul E.
    CHEMISTRY-AN ASIAN JOURNAL, 2019, 14 (13) : 2225 - 2229
  • [6] Photochromism and Photomagnetism Induced by Structural Disorder of a Crystalline Spin-Crossover FeII Complex
    Jin, Ai-Ping
    Chen, Xiang-Yi
    Wang, Ming-Sheng
    Guo, Guo-Cong
    CRYSTAL GROWTH & DESIGN, 2019, 19 (07) : 3688 - 3693
  • [7] Thermally and Photoinduced Spin-Crossover Behavior in Iron(II)-Silver(I) Cyanido-Bridged Coordination Polymers Bearing Acetylpyridine Ligands
    Cruz, Carlos
    Galdames, Jorge
    Camayo-Gutierrez, Liz
    Rouzieres, Mathieu
    Mathoniere, Corine
    Menendez, Nieves
    Audebrand, Nathalie
    Reyes-Lillo, Sebastian E.
    Clerac, Rodolphe
    Venegas-Yazigi, Diego
    Paredes-Garcia, Veronica
    INORGANIC CHEMISTRY, 2024, 63 (38) : 17561 - 17573
  • [8] Slow Dynamics of the Spin-Crossover Process in an Apparent High-Spin Mononuclear FeII Complex
    Ye, Yi Shan
    Chen, Xiu Qin
    Cai, You De
    Fei, Bin
    Dechambenoit, Pierre
    Rouzieres, Mathieu
    Mathoniere, Corine
    Clerac, Rodolphe
    Bao, Xin
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (52) : 18888 - 18891
  • [9] In Situ Ligand Transformation for Two-Step Spin Crossover in FeII[MIV(CN)8]4- (M = Mo, Nb) Cyanido-Bridged Frameworks
    Kawabata, Shintaro
    Chorazy, Szymon
    Zakrzewski, Jakub J.
    Imoto, Kenta
    Fujimoto, Takashi
    Nakabayashi, Koji
    Stanek, Jan
    Sieklucka, Barbara
    Ohkoshi, Shin-ichi
    INORGANIC CHEMISTRY, 2019, 58 (09) : 6052 - 6063
  • [10] Structural phase transition in a multi-induced mononuclear FeII spin-crossover complex
    Zhu, Yuan-Yuan
    Liu, Chang-Wei
    Yin, Ji
    Meng, Zhao-Sha
    Yang, Qian
    Wang, Junhu
    Liu, Tao
    Gao, Song
    DALTON TRANSACTIONS, 2015, 44 (48) : 20906 - 20912
123