Synthesis and characterization of 1,3,5-triaza-7-phosphaadamantane based water-soluble ligands

被引：1

作者：

Bhatia, Anita ^{[1
]}

Muthaiah, Senthilkumar ^{[2
]}

机构：

[1] DIT Univ, Sch Phys Sci, Dept Chem, Dehra Dun 248009, Uttarakhand, India

[2] Natl Inst Technol Kurukshetra, Dept Chem, Kurukshetra, Haryana, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2023年 / 198卷 / 02期

关键词：

Water-soluble ligands; synthesis; spectroscopic characterization; ACCEPTORLESS ALCOHOL DEHYDROGENATION; 2+2+2 ALKYNE CYCLOTRIMERIZATION; TRANSITION-METAL DERIVATIVES; AQUEOUS-MEDIUM; COORDINATION CHEMISTRY; CYCLOPENTADIENYL DERIVATIVES; RUTHENIUM COMPLEX; ORGANIC-REACTIONS; COBALT; CATALYSTS;

D O I：

10.1080/10426507.2022.2116639

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Four new water-soluble bidentate ligands, namely, (cyclopentadienyl)ethyl-1,3,5-triaza-7-phosphadamantane (1), 1,2-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) ethane (2), 1,3-bis-(1,3,5-triaza-7-phosphaaadamantan-6-yl) propane (3) and 1,4-bis-(1,3,5-triaza-7-phosphaadamantan-6-yl) butane (4) have been synthesized and characterized by multi-nuclear NMR (H-1, C-13 and P-31), elemental analysis and mass spectrometry. Compound 1 was synthesized by using two different synthetic routes in excellent yields and is also the first example of water-soluble chelating cyclopentadienyl ligand containing 1,3,5-triaza-7-phosphaadamantane.

引用

页码：122 / 127

页数：6

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