In-situ electrochemical fabrication of Ag@AgCl NW-PET film with superior photocatalytic bactericidal activity

Constructing a composite photocatalyst with efficient charge-transfer pathways is contribute to improving charge separation, which has attracted wide attention owing to its availability in photocatalysis applications. In this work, three-dimensional (3D) silver@silver chloride (Ag@AgCl) network structures are fabricated for photocatalytic inactivation of Escherichia coli (E. coli) by the in situ electrochemical introducing AgCl shell on the surface of Ag nanowire (NW) networks that are coated on a polyethylene terephthalate (PET) substrate. The obtained Ag@AgCl NW-PET films exhibit good photocatalytic bactericidal activity against E. coli under simulated Sunlight irradiation, mainly due to their efficient charge-transport channel constructed by the Ag NWs network. It is worth noting that the content of converted AgCl shell is positively correlated with their photocatalytic bactericidal efficiency. The experimental results also demonstrate that the synergistic contribution of Ag+ sustained release, rough surfaces and energy band structure optimization in photocatalytic sterilization. Besides, the prepared Ag@AgCl NW-PET film can be recycled, and the photocatalytic sterilization efficiency can still keep above 99% after three cycles. This work might provide new and more diverse opportunities for the development of excellent charge-transport, recyclable photocatalysts for photocatalytic sterilization.