Negative CO2 emission from oxy-fuel combustion in CFB boilers

Oxy-combustion by flue-gas recirculation for CO2 capture is applied to an existing, already CO2-neutral, biomass -fired circulating fluidized bed (CFB) boiler, thus resulting in negative CO2 emissions. The required oxygen concentration is determined by a heat balance, but in an existing plant the volume flow is then reduced as well as the fluidization velocity, which affects the heat transfer. Methods to resolve this problem are investigated. The oxygen is usually proposed to be supplied by air separation; a method that consumes a considerable share of the energy produced in the plant. Here, it is instead suggested to use oxygen produced together with hydrogen in electrolysis by excess wind and solar power.