Nitrooxylative Dearomatization Reaction of β-Naphthols with Hypervalent Iodine Reagent

被引：3
|
作者：
Zhang, Shan-Shan [1 ,2 ]
Li, Muzi [2 ]
Gu, Qing [2 ]
You, Shu-Li [1 ,2 ]
机构：
[1] East China Normal Univ, Chang Kung Chuang Inst, 3663 North Zhongshan Rd, Shanghai 200062, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, New Cornerstone Sci Lab, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 13卷 / 04期
基金：
中国国家自然科学基金; 国家重点研发计划;
关键词：
dearomatization; hypervalent iodine reagent; beta-naphthol; nitrooxylative; ASYMMETRIC ALLYLIC DEAROMATIZATION; TERT-BUTYL NITRITE; OXIDATIVE DEAROMATIZATION; ARYLATIVE DEAROMATIZATION; INTRAMOLECULAR DEAROMATIZATION; NITRATE; OXIDE; 2-NAPHTHOLS; EFFICIENT; ALCOHOLS;
D O I：
10.1002/ajoc.202400005
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A catalyst-free intermolecular dearomatization reaction of beta-naphthols with hypervalent-iodine-based nitrooxylating reagent is reported. Various nitrooxylated beta-naphthalenones bearing a quaternary carbon stereogenic center were obtained smoothly in good to excellent yields (up to 87 %) under mild conditions. This method features mild conditions, broad substrate scope and excellent chemoselectivity.
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页数：4
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