Base-Mediated Tandem [3+2] Cycloaddition/Ring Openning Reaction of Arylhydrazonoyl Chlorides with Arylnitroso Compounds for Synthesis of Substituted Diazene Oxides

被引：3

作者：

Li, Yi ^{[1
]}

Xu, Weinan ^{[1
]}

Lei, Xidan ^{[1
]}

Xi, Jiangbo ^{[1
]}

Zou, Jing ^{[1
]}

Wang, Gang ^{[1
]}

He, Zhao-Lin ^{[1
]}

机构：

[1] Wuhan Inst Technol, Engn Res Ctr Phosphorus Resources Dev & Utilizat, Sch Chem & Environm Engn, Key Lab Green Chem Engn Proc,Minist Educ,Hubei Ke, Wuhan 430205, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2023年 / 88卷 / 19期

基金：

中国国家自然科学基金;

关键词：

NITRILE IMINES; 1,3-DIPOLAR CYCLOADDITION; NITROSOBENZENES; BIOSYNTHESIS; NITRILIMINES; PERFORMANCE; DERIVATIVES; AZO;

D O I：

10.1021/acs.joc.3c01427

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A base-mediated tandem [3 + 2] cycloaddition/ring opening reaction of nitrilimines generated from arylhydrazonoyl chlorides with arylnitroso compounds has been developed. This protocol provides a novel and rapid approach for the synthesis of substituted azoxy compounds under mild conditions with moderate to good yields and a broad substrate scope.

引用

页码：14200 / 14204

页数：5

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