Hg3Se(SeO3)(SO4): A Mixed-Valent Selenium Compound with Mid-Infrared Transmittance Obtained by In Situ Reaction

被引：14
|
作者：
Li, Peng-Fei [1 ,2 ,3 ]
Hu, Chun-Li [1 ,2 ]
Li, Bing-Xuan [1 ]
Mao, Jiang-Gao [1 ,2 ,3 ]
Kong, Fang [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
来源：
INORGANIC CHEMISTRY | 2024年 / 63卷 / 09期
基金：
中国国家自然科学基金;
关键词：
CRYSTAL;
D O I：
10.1021/acs.inorgchem.4c00033
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Exploring new material systems is a highly significant task in the field of inorganic chemistry. A new mixed-valent selenium compound, Hg3Se(SeO3)(SO4), was successfully synthesized through in situ reactions. This compound exhibits a novel three-dimensional structure composed of Hg3Se(SO4) layers bridged by SeO3 trigonal pyramids. It is the first structure containing (SeO3)(2-), (SO4)(2-), and Se2- simultaneously. In addition, Hg3Se(SeO3)(SO4) possesses a wide bandgap (3.5 eV), moderate birefringence (Cal:0.064@546 nm, Exp:0.069@546 nm), a high laser-induced damage threshold (23.35 MW cm(-2)), and a wide transmittance window (0.28-6.6 mu m). Our work demonstrates that mixed-valent (+4, -2) selenite selenide can be potential optical materials for the mid-infrared region.
引用
收藏
页码：4011 / 4016
页数：6
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