Construction of BiOCl/Ti-MOFs type-II heterojunction photocatalyst for enhanced photocatalytic performance for multiple antibiotics removal

The increased threats to environmental and human health caused by the widespread use of antibiotics have increased the need for efficient technologies for removing antibiotic remnants from wastewater after production. Photocatalysis, which is non-toxic, highly efficient, and low energy consumption, has played a vital role in wastewater treatment among the aforementioned technologies. Therefore, a MIL-125(Ti)/BiOCl type-II heterojunction photocatalyst was fabricated using solvothermal method. Investigations remarkably revealed that the enhanced photocatalytic performance of the photocatalyst for multiple antibiotics degradation (tetracycline and ofloxacin) was attributed to the construction of a heterojunction, which inhibits carrier recombination and enhances visible-light absorption. Furthermore, the radical trapping experiments and electron spin resonance determined superoxide radicals and holes to be the main species in the photocatalytic process. Finally, we presented a potential photocatalytic mechanism that could account for the observations. Overall, this study offered guidelines for developing more photocatalysts with visible-light responses and removing multiple antibiotics from water more efficiently.