Progress in the Preparation and Application of Arylsilane

被引:1
|
作者
Liu, Jun [1 ]
Peng, Jiajian [1 ]
Bai, Ying [1 ]
Li, Jiayun [1 ]
Song, Zijie [1 ]
Liu, Peng [1 ]
Ouyang, Ting [1 ]
Lan, Huilin [1 ]
Huang, Yichen [1 ]
机构
[1] Hangzhou Normal Univ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Key Lab Organosilicon Mat Technol Zhejiang Prov,Mi, Hangzhou 311121, Zhejiang, Peoples R China
关键词
Arylsilane; synthesis; catalytic; property; application; review; C-H SILYLATION; PALLADIUM-CATALYZED SILYLATION; DEHYDROGENATIVE SILYLATION; ARYL HALIDES; COUPLING REACTIONS; BONDS; CHLORIDES; ARENES; HYDROSILANES; ARYLATION;
D O I
10.2174/1385272827666230217093032
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Arylsilanes are the basic raw material for the synthesis of advanced silicone new materials such as phenylsilicone resin, phenylsilicone oil and phenyl silicone rubber, etc. The silicone polymers containing aryl groups were applied widely in the fields including electronics, and aerospace. In the past decades, arylsilanes have been widely used in organic synthesis, such as Hiyama coupling, C-N bond formation, synthesis of biaryl, polyketone polymer, and so on. Therefore, synthetic research on arylsilanes has also received wide attention. In this paper, the research progress of the synthesis and applications of arylsilanes in the past decades has been reviewed.
引用
收藏
页码:28 / 37
页数:10
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