Recent advances and prospects in electrochemical coupling technologies for metal recovery from water

With the development of our society, the desire to recover valuable metal resources from metal-containing wastewaters or natural water bodies is becoming increasingly stronger nowadays. To overcome the limitations of single techniques, coupling technologies with synergistic effects are attracting increasing attention regarding metal resource recovery from water with particular interest in electrochemical coupling technologies in view of the advantages of electrochemical methods. This state-of-the-art review comprehensively presented the mechanisms and performance of electrochemical coupling systems for metal recovery from water. To give a clear overview of current research trends, technologies coupled with electrochemical processes can be categorized into six main types: electrochemical techniques, membrane modules, adsorption/extraction techniques, sonication technologies, energy supply techniques and others. The electrochemical coupling system has shown synergistic