Continuous Flow Synthesis of Group 11 Metal-NHC Complexes [M(IPr)(OC(H)(CF3)2)] (with M=Cu, Ag and Au)

被引：1
|
作者：
Simoens, Andreas [1 ]
Cari, Gianluca [2 ,3 ]
Ostrowska, Sylwia [2 ,3 ]
Cazin, Catherine S. J. [2 ,3 ]
Stevens, Christian V. [1 ]
Nolan, Steven P. [2 ,3 ]
机构：
[1] Univ Ghent, Dept Green Chem & Technol, Synth Bioresources & Bioorgan Chem Res Grp, Coupure Links 653, B-9000 Ghent, Belgium
[2] Univ Ghent, Dept Chem, Krijgslaan 281, S-3, B-9000 Ghent, Belgium
[3] Univ Ghent, Ctr Sustainable Chem, Krijgslaan 281, S-3, B-9000 Ghent, Belgium
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2024年 / 13卷 / 04期
基金：
比利时弗兰德研究基金会;
关键词：
Flow Chemistry; Organometallic; Group; 11; Metals; N-Heterocyclic Carbene; Weak Base Method; HETEROCYCLIC CARBENE COMPLEXES;
D O I：
10.1002/ajoc.202400013
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The weak base method in continuous flow is currently one of the most sustainable and attractive approaches towards the synthesis of transition metal N-heterocyclic carbene (NHC) complexes. Herein we broaden the scope of this method by using it to produce [M(IPr)(OC(H)(CF3)(2))] complexes, including copper, silver, and gold. These compounds bear the alkoxide ligand within the coordination sphere of the catalysts, which can open up new ways to benefit from the unique properties offered by HFIP (1,1,1,3,3,3-hexafluoroisopropanol) in catalysis, while minimizing the needed amount.
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页数：5
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