Energy and exergy analysis of a thermoelectric generator system for automotive exhaust waste heat recovery

Thermoelectric generators are a viable solution for recovering and producing energy utilizing wasted energy in automotive exhaust. Exergy analysis can help identify irreversible losses that occur during the transfer of exhaust energy, which is essential for comprehending and developing exhaust thermoelectric generator systems. In this study, we proposed a model based on thermodynamic of the exhaust thermoelectric generator and conducted energy and exergy analyses. The results indicate that convective heat transfer exergy loss and PN junction thermal conductivity exergy loss are the primary exergy losses of the exhaust thermoelectric generator, accounting for more than 52.0 % of the total. Increasing the temperature of exhaust can boost the performance of systems, but it may also reduce the proportion of available energy obtained by the cooling water. When the exhaust heat transfer coefficient is increased to 300, the convective exergy losses of the exhaust can be reduced to 17.6 %, resulting in an overall exergy efficiency of 38.8 %. Furthermore, by increasing the exhaust flow rate from 10 g/s to 50 g/s, the power generation capacity has increased by a factor of 6.87, with little change in exergy losses. These findings are valuable for developing high-efficiency exhaust power generators.