Multi-criteria thermoeconomic optimization of a geothermal energy-driven green hydrogen production plant coupled to an alkaline electrolyzer

Among the various technologies for hydrogen production, the renewable energy driven water electrolysis has emerged as a favorable method. In this respect, the present research proposes and analyses a novel and efficient medium-temperature driven geothermal system for green hydrogen production. An alkaline electrolyzer is deployed for hydrogen production which is powered by a double flash steam geothermal power cycle. To boost the power generation (and hence the hydrogen production amount) the double flash cycle is equipped with a selfsuperheating process, which superheats the saturated vapor at turbine inlet without using another external heat source. Thermodynamic evaluations, based on exergy concept, along with economic analysis are carried out to assess the hydrogen production amount, plant exergy efficiency and total cost rate, and the unit hydrogen price. In order to represent a comprehensive investigation of the plant performance, parametric analyses along with single- and multi-criteria optimizations were conducted. The results revealed that, for 1kg/s of geothermal brine, the capacity of hydrogen production of the proposed plant is similar to 1.5 -3kg/h under various operating conditions. It is found that, under multi-objective optimum operating conditions, the plant yields 12.63% exergy efficiency and its total cost rate is calculated to be 10.42 $/h. However, if the plant is to be optimized for maximum exergy efficiency, the value of 14.25% is achievable which will result in increment of total cost rate to 11.97 $/h.