High strength injection molding welding and interface crystal phase changes in polyamide 6

被引:2
|
作者
Wu, Haonan [1 ]
Qiu, Jianhui [1 ,4 ]
Zhang, Guohong [2 ]
Sakai, Eiichi [1 ]
Zhao, Wei [1 ]
Tang, Jianhua [1 ]
Wu, Hong [3 ]
Guo, Shaoyun [3 ]
机构
[1] Akita Prefectural Univ, Fac Syst Sci & Technol, Dept Mech Engn, Akita, Japan
[2] Shanxi Expressway Test & Inspect Co Ltd, Xian, Peoples R China
[3] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu, Peoples R China
[4] Akita Prefectural Univ, Fac Syst Sci & Technol, Dept Mech Engn, Akita 0150055, Japan
来源
POLYMER ENGINEERING AND SCIENCE | 2023年 / 63卷 / 10期
关键词
crystalline phase; Fourier-transform infrared; injection molding; interface; microhardness; polyamide; 6; welding strength; ISOTACTIC POLYPROPYLENE; MOLDED POLYPROPYLENE; CRYSTALLIZATION; MORPHOLOGY; QUALITY; SHEAR; THERMOPLASTICS; COMPOSITES; GEOMETRY; FAILURE;
D O I
10.1002/pen.26446
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Injection molding is a widely used method for production of plastic components, offering both simplicity and high strength. In this study, secondary injection molding was utilized to weld polyamide 6 (PA6). The welded samples were evaluated for the welding strength via a shear tensile test. Three process parameters of mold temperature, injection temperature, and injection speed were varied to determine the optimal conditions for welding. A polarizing microscope analysis of the welding interface revealed formation of a shish kebab layer (SKL) structure, which significantly contributed to the welding strength. A differential scanning calorimetry analysis of the welded samples showed that changes in the crystallinity at the interface were closely related to the welding strength under different injection molding conditions. To analyze the crystal phase of the interface after welding, we propose the use of Fourier-transform infrared spectroscopy area scanning to obtain the relationship between the phase transformation and welding strength. Additionally, microhardness testing is proposed as a means of evaluation of the welding effect. Overall, this study highlights the importance of optimization of process parameters in secondary injection molding to achieve strong welds in PA6, where the SKL structure and crystallinity changes at the interface have crucial roles. Highlights center dot The high welding shear strength reaches 80% of the base material. center dot The interfacial crystalline structure has a significant impact on the strength. center dot The crystalline changes were analyzed using FTIR region scanning. center dot The relationship between microhardness and welding strength was obtained. center dot The wide-ranging conditions have reference value for industrial production.
引用
收藏
页码:3313 / 3327
页数:15
相关论文
共 50 条
  • [1] Effects of interfacial structure and molding condition on the injection welding strength of polyamide
    Department of Mechine Intelligence and Systems Engineering, Faculty of Science and Technology, Akita Prefectoral University, 84-4 Tsuchiya-Ebinokuchi, Yurihonjyo-shi, Akita, 015-0055, Japan
    Nihon Kikai Gakkai Ronbunshu A, 2006, 9 (1413-1420):
  • [2] Distribution and reinforcement effect of carbon fiber at the interface in injection welding of polyamide 6 composites
    Wu, Haonan
    Qiu, Jianhui
    Zhang, Guohong
    Sakai, Eiichi
    Zhao, Wei
    Tang, Jianhua
    Wu, Hong
    Guo, Shaoyun
    POLYMER COMPOSITES, 2024, 45 (02) : 1347 - 1360
  • [3] Foaming of Polyamide 6 in the Process of Injection Molding.
    Misterek, Boguslaw
    Rzezak, Lech
    Polimery/Polymers, 1977, 22 (06) : 220 - 223
  • [4] Effect of the temperature gradient on the interfacial strength of polyethylene/polyamide 6 during the sequential injection molding
    Zhang, Xianlong
    Jiang, Genjie
    Wu, Hong
    Guo, Shaoyun
    HIGH PERFORMANCE POLYMERS, 2014, 26 (02) : 135 - 143
  • [5] Effects of interfacial morphology on the welding strength of injection-molded polyamide
    Qiu, Jianhui
    Tsuboi, Atsushi
    Izumi, Kazuo
    Wu, Hong
    Guo, Shaoyun
    Huang, Yudong
    POLYMER ENGINEERING AND SCIENCE, 2007, 47 (12): : 2164 - 2171
  • [6] Heterogeneous Dispersion of the Compatibilizer in the Injection Molding of Polyamide 6/Polypropylene Blends
    Yang, Wei
    Tang, Xue-Gang
    Xie, Bang-Hu
    Zhu, Yong-Ping
    Yang, Ming-Bo
    Hou, Meng
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 113 (01) : 299 - 305
  • [7] Polymorphism in polyamide 6 and polyamide 6/clay nanocomposites molded via water-assisted injection molding
    Huang, Han-Xiong
    Wang, Bin
    Zhou, Wei-Wen
    COMPOSITES PART B-ENGINEERING, 2012, 43 (03) : 972 - 977
  • [8] Polyamide-6/vegetal fiber composite prepared by extrusion and injection molding
    Santos, Paulo A.
    Spinace, Marcia A. S.
    Fermoselli, Karen K. G.
    De Paoli, Marco-A.
    COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2007, 38 (12) : 2404 - 2411
  • [9] Obtaining nanocomposites of polyamide 6 and cellulose whiskers via extrusion and injection molding
    Correa, Ana Carolina
    Teixeira, Eliangela de Morais
    Carmona, Vitor Brait
    Ricardo Teodoro, Kelcilene Bruna
    Ribeiro, Caue
    Capparelli Mattoso, Luiz Henrique
    Marconcini, Jose Manoel
    CELLULOSE, 2014, 21 (01) : 311 - 322
  • [10] Obtaining nanocomposites of polyamide 6 and cellulose whiskers via extrusion and injection molding
    Ana Carolina Corrêa
    Eliangela de Morais Teixeira
    Vitor Brait Carmona
    Kelcilene Bruna Ricardo Teodoro
    Cauê Ribeiro
    Luiz Henrique Capparelli Mattoso
    José Manoel Marconcini
    Cellulose, 2014, 21 : 311 - 322