Flower-like FeCoNi ternary composite formed by interweaving nano needles for positive electrode material of supercapacitor

被引:15
|
作者
Zhou, Hao [1 ]
Wang, Xiao-Lu [3 ]
Nasser, Ramzi [2 ]
Jiang, Tian-Tian [1 ]
Li, Zhou [2 ]
Song, Ji-Ming [1 ,2 ]
机构
[1] Anhui Univ, Sch Chem & Chem Engn, Key Lab Struct & Funct Regulat Hybrid Mat, Minist Educ, Hefei 230601, Anhui, Peoples R China
[2] Anhui Univ, Sch Mat Sci & Engn, Anhui Prov Key Lab Chem Inorgan Organ Hybrid Funct, Hefei 230601, Anhui, Peoples R China
[3] Bozhou Univ, Sch Biol & Food Engn, Bozhou 236800, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Layered Double Hydroxide; FeCoNi-LDH; Hydrothermal method; Asymmetric supercapacitor; LAYERED DOUBLE HYDROXIDE; ENERGY-STORAGE; ANODE MATERIAL; PERFORMANCE; NI; GRAPHENE; NANOSHEET; LDH; MICROSPHERES; ARCHITECTURE;
D O I
10.1016/j.jallcom.2023.172952
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ternary layered double hydroxide (LDH) are potential electrode material choices for supercapacitors (SCs) due to their various oxidation states and high theoretical specific capacitance. In this paper, FeCoNi-LDH composite with cross-braided flowers of nanoneedles has been prepared by a single-step hydrothermal method. By highlighting the structural and morphological advantages, the obtained ternary LDH shows lower resistivity in comparison with the binary LDH. As electrode material, the ternary LDH exhibits excellent electrochemical properties, such as superb specific capacitance of 2163.3 F & sdot;g  1 at 0.5 A & sdot;g  1 and good cycle retention rate of 93.8% after 5000 cycles at 20 A & sdot;g  1. Meanwhile, the assembled asymmetric flexible solid-state supercapacitor device can provide 44.8 Wh & sdot;kg  1 energy density at 807.5 W & sdot;kg  1. Moreover, two devices in series can also light up miniature light bulbs of different hues and maintain them for a long period when they are connected in series.
引用
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页数:12
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