Synthesis and solubility properties of amine-functionalized fulleropyrrolidines in organic solvents

被引：0
|
作者：
Lim, Suk Hyun [1 ]
Cho, Dae Won [1 ,2 ]
机构：
[1] Yeungnam Univ, Dept Chem, Gyongsan, Gyeongbuk, South Korea
[2] Yeungnam Univ, Dept Chem, Gyongsan 38541, Gyeongbuk, South Korea
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2023年 / 44卷 / 11期
关键词：
fullerene; fulleropyrrolidines; N-alkylglycinates; organic solvent; solubility; FULLERENE DERIVATIVES; ELECTRON-TRANSFER; C-60;
D O I：
10.1002/bkcs.12769
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this study, we prepared amine-functionalized fullerene derivatives by using methylene blue (MB)-sensitized photoaddition reactions of fullerene C-60 with a variety of a-silyl group containing N-alkylglycinates through 1,3-dipolar cycloaddition reactions of in situ formed azomethine ylide, derived from glycinates, to fullerene C-60 and examined their solubility properties in several organic solvents. The results showed that although it was hard to find a clear correlation between the solvent solubility of and N-substituents of fullereopyrrolidines, the solubility of functionalized fullerene derivatives in organic solvents such as toluene, CHCl3, CH2Cl2, and tetrahydrofuran (THF) was much higher than that of C-60 and in addition, the solubility properties of fullereopyrrolidines can be manipulated by incorporating diverse organic moieties into fullerene surface.
引用
收藏
页码：911 / 915
页数：5
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