Effect of Complexation with Modified β-Cyclodextrins on the Luminescent Properties of Bisphenol A in Aqueous Solution

被引:0
|
作者
Belikov, Yu. A. [1 ,2 ]
Zhdankin, G. I. [1 ,2 ]
Marikovskaya, S. M. [2 ,3 ]
Sulima, M. T. [2 ,4 ]
Pozdnyakov, I. P. [1 ,2 ]
机构
[1] Russian Acad Sci, Voevodsky Inst Chem Kinet & Combust, Siberian Branch, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[4] Russian Acad Sci, Inst Chem Biol & Fundamental Med, Siberian Branch, Novosibirsk 630090, Russia
关键词
D O I
10.1134/S0018143923090023
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, the effect of substituted beta-cyclodextrins on the photophysical properties of their complexes with bisphenol A has been studied using a fluorescent method. Data on the quantum yields of fluorescence were obtained for the first time for a number of bisphenol A complexes with substituted beta-cyclodextrins. It has been shown that the binding of bisphenol into a complex significantly increases the lifetime of an excited state and the quantum yield of fluorescence due to the shielding of its excited state from solvent quenching by the beta-cyclodextrin molecule.
引用
收藏
页码:S386 / S390
页数:5
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