Rhenium complex-catalyzed N-allylation and N-benzylation of amines with alcohols

被引：3
|
作者：
Umeda, Rui [1 ]
Shimaoka, Shiori [1 ]
Mori, Shintaro [1 ]
Takagishi, Tsubasa [1 ]
Nishiyama, Yutaka [1 ]
机构：
[1] Kansai Univ, Fac Chem Mat & Bioengn, Suita, Osaka 5648680, Japan
来源：
TETRAHEDRON LETTERS | 2023年 / 119卷
关键词：
Rhenium; Allylation benzylation; Alcohols; Amines; ALLYLIC ALCOHOLS; ENOL ACETATES; PALLADIUM; AMINATION; ALKYLATION; TRANSPOSITION; BONDS; OXIDE;
D O I：
10.1016/j.tetlet.2023.154412
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
When aliphatic amines were allowed to react with allylic alcohols in the presence of a catalytic amount of a rhenium complex, the N-allylation of aliphatic amines efficiently proceeded to give the corresponding N-allyl substituted amines in moderate to good yields. Similarly, the N-benzylation of an amine with ben-zylic alcohols occurred in the presence of the rhenium catalyst. (c) 2023 Elsevier Ltd. All rights reserved.
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页数：4
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