Effects of polycyclic aromatic hydrocarbons fluoranthene on the soil aggregate stability and the possible underlying mechanism

Soil contamination by polycyclic aromatic hydrocarbons (PAHs) is an increasing problem in many countries, impacting the ecological environment's sustainable development. This study investigated the effects of fluoranthene (Fla) on soil aggregate stability. A possible mechanism for the interaction of Fla with soil aggregates was proposed by characterizing the aggregate structure. The results showed that Fla significantly improved the aggregate stability in the concentration range of 0-30.0 mg/kg. The content of macro-aggregates reached the maximum value at 10 mg/kg of Fla, which increased by 24.25% compared with the control group, while the content of large-aggregates decreased by 12.11%. Meanwhile, the mean weight diameter (MWD) and geometric mean diameter (GMD) increased by 56.63% and 37.66%, respectively. However, the macro-aggregates zeta potential value and specific surface area (SSA) decreased by 12.68% and 13.61%, respectively. The cracks of macroaggregates were also significantly reduced. In addition, Fla-based free radicals were detected on the macro-aggregates. The absorption peak of the C-O group significantly increased, indicating that Fla may be covalently bound to the aggregates by aromatic ether bonds, which is a possible mechanism for the interaction between Fla and aggregates. This study provides theoretical support for revealing the effects of PAHs on soil.