Mesoporous ordered titania films: An advanced platform for photocatalysis

被引:16
|
作者
Innocenzi, Plinio [1 ]
Malfatti, Luca [1 ]
机构
[1] Univ Sassari, Dept Biomed Sci, Lab Mat Sci & Nanotechnol LMNT, CR INSTM, I-07100 Sassari, Italy
关键词
Photocatalysis; Titania; Mesoporous films; Heterostructures; Self; -assembly; TIO2; THIN-FILMS; VISIBLE-LIGHT PHOTOCATALYSIS; PORE ARCHITECTURE; SURFACE; UV; CHEMISTRY; GRAPHENE; DIOXIDE; DESIGN; WATER;
D O I
10.1016/j.jphotochemrev.2023.100646
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mesoporous materials possess unique structural characteristics, such as high surface area, large pore volume, and interconnected pore networks, which make them ideal candidates for photocatalysis. The objective of this review is to critically analyse the synthesis methods, characterization techniques, and photocatalytic performance of mesoporous titania films for photocatalysis. The article begins by providing a short overview of the chemicalphysical processes involved in photocatalysis of titania. It highlights the need for efficient photocatalytic materials with enhanced surface area and light harvesting capabilities. Subsequently, the synthesis methods for creating mesoporous titania films are discussed, including sol-gel chemistry, templating approaches, and selfassembly techniques. Emphasis is placed on the control of pore size, distribution, and film thickness to optimize the photocatalytic performance. The influence of synthesis parameters on the film porosity, crystallinity, and surface area is examined in detail. Furthermore, the review highlights recent advancements in the field, including strategies to enhance the photocatalytic performance of mesoporous titania films through doping, surface modification, and heterostructure formation. These approaches aim to improve the light absorption, charge separation, and reactant accessibility, thus maximizing the utilization of solar energy for efficient photocatalysis. In conclusion, mesoporous titania films demonstrate great potential as effective photocatalytic materials. Their unique structural features, combined with proper synthesis and characterization, contribute to enhanced photocatalytic performance. Further research and development in this area may lead to the design and fabrication of advanced mesoporous titania films for a wide range of environmental and energy applications.
引用
收藏
页数:16
相关论文
共 50 条
  • [1] Ytterbium stabilized ordered mesoporous titania for near-infrared photocatalysis
    Li, Zhen-Xing
    Shi, Fu-Bo
    Zhang, Tao
    Wu, Hao-Shuai
    Sun, Ling-Dong
    Yan, Chun-Hua
    CHEMICAL COMMUNICATIONS, 2011, 47 (28) : 8109 - 8111
  • [2] Enhanced Photocatalysis by Doping Cerium into Mesoporous Titania Thin Films
    Zhang, Yu
    Yuwono, Akhmad Herman
    Wang, John
    Li, Jun
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (51): : 21406 - 21412
  • [3] Preparation and photoelectric properties of ordered mesoporous titania thin films
    Shen, Yue
    Tao, Junchao
    Gu, Feng
    Huang, Lu
    Bao, Jian
    Zhang, Jiancheng
    Dai, Ning
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 474 (1-2) : 326 - 329
  • [4] Highly crystallized mesoporous titania thin films for photocatalysis application.
    Tang, J
    Wu, YY
    Stucky, GD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U1425 - U1425
  • [5] Hierarchical ordered macro/mesoporous titania with a highly interconnected porous structure for efficient photocatalysis
    Zhao, Tao
    Ren, Yuan
    Yang, Jianping
    Wang, Lianjun
    Jiang, Wan
    Elzatahry, Ahmed A.
    Alghamdi, Abdulaziz
    Deng, Yonghui
    Zhao, Dongyuan
    Luo, Wei
    JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (42) : 16446 - 16453
  • [6] Visible-light photocatalysis in titania-based mesoporous thin films
    Soni, Saurabh S.
    Henderson, Mark J.
    Bardeau, Jean-Francois
    Gibaud, Alain
    ADVANCED MATERIALS, 2008, 20 (08) : 1493 - +
  • [7] Critical aspects in the production of periodically ordered mesoporous titania thin films
    Soler-Illia, Galo J. A. A.
    Angelome, Paula C.
    Cecilia Fuertes, M.
    Grosso, David
    Boissiere, Cedric
    NANOSCALE, 2012, 4 (08) : 2549 - 2566
  • [8] THERMAL CONDUCTIVITY OF HIGHLY ORDERED AMORPHOUS AND CRYSTALLINE MESOPOROUS TITANIA THIN FILMS
    Coquil, Thomas
    Pilon, Laurent
    Reitz, Christian
    Brezesinski, Torsten
    Nemanick, Joseph E.
    Tolbert, Sarah H.
    PROCEEDINGS OF THE ASME INTERNATIONAL HEAT TRANSFER CONFERENCE - 2010, VOL 6: MICROCHANNELS, NANO, NANOFLUIDS, SPRAY COOLING, POROUS MEDIA, 2010, : 495 - 503
  • [9] Thick titania films for semiconductor photocatalysis
    Andrew Mills
    George Hill
    Matthew Crow
    Stephanie Hodgen
    Journal of Applied Electrochemistry, 2005, 35 : 641 - 653
  • [10] Thick titania films for semiconductor photocatalysis
    Mills, Andrew
    Hill, George
    Crow, Matthew
    Hodgen, Stephanie
    Journal of Applied Electrochemistry, 2005, 35 (7-8): : 641 - 653