Flexible supercapacitors based on vertical graphene/carbon fabric with high rate performance

被引:22
|
作者
Yao, Zehan [1 ]
Quan, Baogang [2 ,3 ,4 ]
Yang, Tianzhong [2 ]
Li, Junjie [2 ]
Gu, Changzhi [2 ]
机构
[1] Lund Univ, Dept Chem, Div Chem Phys, Box 124, SE-22100 Lund, Sweden
[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
[3] Songshan Lake Mat Lab, Dongguan 523808, Guangdong, Peoples R China
[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
Flexible supercapacitors; High rate performance; Vertical graphene; NANOPARTICLES; CAPACITANCE;
D O I
10.1016/j.apsusc.2022.155535
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Vertical graphene (VG) is a remarkable electrode material for supercapacitors due to its large specific area, open channel structures, and numerous exposed edges with high electrochemical activity. However, flexible super -capacitors with high rate performance based on VG have yet to be investigated. Here, we report flexible supercapacitors based on VG, carbon fabric (CF) current collector, and H2SO4 gel polymer electrolyte. VG/CF presents an exceptional electrochemical performance in H2SO4 compared with other aqueous and liquid ion electrolytes. The flexible VG/CF supercapacitor demonstrates a 73% capacitance retention after increasing the charge-discharge rate by 200 times from 0.1 mA cm-2 to 20 mA cm-2. This high rate performance facilitates a high power density of 13.2 mW cm-2 with an energy density of 86.6 mu Wh cm-2. Furthermore, the electro-chemical performances remain mostly unchanged after long-term charge-discharge cycles and mechanical bending. Our results demonstrate a flexible VG/CF supercapacitor with outstanding rate performance and sta-bility for innovative high power energy and electronic devices.
引用
收藏
页数:6
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