Chromium doping enabled improvement in alkaline seawater oxidation over cobalt carbonate hydroxide nanowire array

被引：13

作者：

Zhang, Min ^{[1
]}

He, Xun ^{[1
]}

Dong, Kai ^{[2
]}

Zhang, Hui ^{[1
]}

Yao, Yongchao ^{[2
]}

Yang, Chaoxin ^{[1
]}

Yue, Meng ^{[1
]}

Sun, Shengjun ^{[1
]}

Sun, Yuntong ^{[1
]}

Zheng, Dongdong ^{[1
]}

Luo, Yongsong ^{[2
]}

Liu, Qian ^{[3
]}

Li, Na ^{[1
]}

Tang, Bo ^{[1
,4
]}

Liu, Jun ^{[5
]}

Sun, Xuping ^{[1
,2
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China

[2] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Sichuan, Peoples R China

[3] Chengdu Univ, Inst Adv Study, Chengdu 610106, Sichuan, Peoples R China

[4] Laoshan Lab, Qingdao 266237, Shandong, Peoples R China

[5] Sichuan Univ, West China Hosp, Dept Otolaryngol Head & Neck Surg, Chengdu 610041, Sichuan, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 64期

基金：

中国国家自然科学基金;

关键词：

OXYGEN EVOLUTION REACTION;

D O I：

10.1039/d3cc02667a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The presence of chlorine species in seawater can cause severe anode corrosion, highlighting the critical need for the design of efficient and robust electrocatalysts towards the oxygen evolution reaction (OER) for hydrogen production. Herein, we present a chromium doped cobalt carbonate hydroxide nanowire array on nickel foam (Cr-CoCH/NF) as an effective OER electrocatalyst in seawater. In alkaline conditions, Cr-CoCH/NF exhibits a low overpotential of 450 mV to achieve 500 mA cm(-2), surpassing that of CoCH/NF (614 mV). Additionally, it demonstrates 200 h of continuous oxygen evolution testing.

引用

页码：9750 / 9753

页数：4

共 20 条

[1] Improved Electrochemical Alkaline Seawater Oxidation over Cobalt Carbonate Hydroxide Nanowire Array by Iron Doping
Shi, Shaorui
Sun, Shengjun
He, Xun
Zhang, Longcheng
Zhang, Hui
Dong, Kai
Cai, Zhengwei
Zheng, Dongdong
Sun, Yuntong
Luo, Yongsong
Liu, Qian
Ying, Binwu
Tang, Bo
Sun, Xuping
Hu, Wenchuang
INORGANIC CHEMISTRY, 2023, 62 (30) : 11746 - 11750
[2] Cobalt carbonate hydroxide hydrate nanowire array modified by sulfur doping for aqueous asymmetric supercapacitors
Xiao, Ting
Wang, Zhixin
Jiang, Tao
Yao, Yushuai
Jiang, Lihua
Xiang, Peng
Ni, Shibing
Tan, Xinyu
CHEMICAL ENGINEERING JOURNAL, 2022, 432
[3] Chromium doping: A new approach to regulate electronic structure of cobalt carbonate hydroxide for oxygen evolution improvement
Zhao, Jinxiu
Liu, Xuejing
Ren, Xiang
Du, Bing
Kuang, Xuan
Tian, Dongxu
Wei, Qin
Wu, Dan
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 609 : 414 - 422
[4] Boosting Alkaline Seawater Oxidation of CoFe-layered Double Hydroxide Nanosheet Array by Cr Doping
Yao, Yongchao
Yang, Chaoxin
Sun, Shengjun
Zhang, Hui
Geng, Meiqi
He, Xun
Dong, Kai
Luo, Yonglan
Zheng, Dongdong
Zhuang, Weihua
Alfaifi, Sulaiman
Farouk, Asmaa
Hamdy, Mohamed S.
Tang, Bo
Zhu, Shuyun
Sun, Xuping
Hu, Wenchuang
SMALL, 2024, 20 (13)
[5] CoFe Hydroxide Nanospheres for Enhanced Alkaline Water Splitting and Seawater Oxidation:Anion Doping Effects of Fluorine and Carbonate
Zheng, Tingting
Shi, Junyu
Wang, Dandan
Min, Yulin
Xu, Qunjie
Li, Qiaoxia
CHEMISTRY-A EUROPEAN JOURNAL, 2025, 31 (05)
[6] Enhancing the stability of NiFe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping
Yao, Yongchao
Sun, Shengjun
Zhang, Hui
Li, Zixiao
Yang, Chaoxin
Cai, Zhengwei
He, Xun
Dong, Kai
Luo, Yonglan
Wang, Yan
Ren, Yuchun
Liu, Qian
Zheng, Dongdong
Zhuang, Weihua
Tang, Bo
Sun, Xuping
Hu, Wenchuang
JOURNAL OF ENERGY CHEMISTRY, 2024, 91 : 306 - 312
[7] Enhancing the stability of Ni Fe-layered double hydroxide nanosheet array for alkaline seawater oxidation by Ce doping
Yongchao Yao
Shengjun Sun
Hui Zhang
Zixiao Li
Chaoxin Yang
Zhengwei Cai
Xun He
Kai Dong
Yonglan Luo
Yan Wang
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Qian Liu
Dongdong Zheng
Weihua Zhuang
Bo Tang
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Journal of Energy Chemistry, 2024, 91 (04) : 306 - 312
[8] Selective Electrochemical Alkaline Seawater Oxidation Catalyzed by Cobalt Carbonate Hydroxide Nanorod Arrays with Sequential Proton-Electron Transfer Properties
Li, Gang
Li, Fusheng
Zhao, Yilong
Li, Wenlong
Zhao, Ziqi
Li, Yingzheng
Yang, Hao
Fan, Ke
Zhang, Peili
Sun, Licheng
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2021, 9 (02) : 905 - 913
[9] Doping-induced facet transformation boosts water oxidation activity of cobalt carbonate hydroxide hydrate
Liu, Xue-Ying
Bi, Haohao
Li, Lei
Li, Bo
Wang, Yu-Han
Shi, Jinghui
Nie, Jianhang
Huang, Gui-Fang
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APPLIED PHYSICS LETTERS, 2023, 123 (09)
[10] Ni(OH)2 nanoparticles encapsulated in conductive nanowire array for high-performance alkaline seawater oxidation
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Jiaqian Wang
Pengyu Liu
Jie Liang
Yongsong Luo
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Bo Tang
Qian Liu
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Nano Research, 2022, 15 : 6084 - 6090

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