An Inorganic Fluorescent Chemosensor: Rational Design and Selective Mg2+ Detection

被引：1
|
作者：
Gerard, Theodore [1 ]
Wei, Yang [1 ]
Weerawardhana, Erwin [1 ]
Lugosan, Adriana [1 ]
Zeller, Matthias [2 ]
Dickie, Diane A. [3 ,4 ]
Li, Pengfei [1 ]
Lee, Wei-Tsung [1 ]
机构：
[1] Loyola Univ Chicago, Dept Chem & Biochem, Chicago, IL 60660 USA
[2] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
[3] Brandeis Univ, Dept Chem, Waltham, MA 02453 USA
[4] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
来源：
ACS OMEGA | 2023年
基金：
美国国家科学基金会;
关键词：
COORDINATION POLYMERS; MOLECULAR-STRUCTURES; METAL-IONS; MAGNESIUM; COMPLEXES; GEOMETRY; ELEMENTS; DATABASE; CRYSTAL; MESPEUS;
D O I：
10.1021/acsomega.2c06058
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A Zn2+ based complex, 3, displays greatly increased fluorescence emission in the presence of Mg2+. Fluorescent and computational studies suggest that 3 selectively interacts with Mg2+ due to optimal cavity size formation between two uncoordinated pyrazole side arms. This work thus represents a new approach to the development of fluorescent chemosensors.
引用
收藏
页码：3835 / 3841
页数：7
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