Recycling of a post-industrial printed multilayer plastic film containing polyurethane inks by solvent-targeted recovery and precipitation

被引:12
|
作者
Sanchez-Rivera, Kevin L.
Munguia-Lopez, Aurora del Carmen
Zhou, Panzheng [1 ]
Cecon, Victor S. [2 ]
Yu, Jiuling [1 ]
Nelson, Kevin [3 ]
Miller, Daniel [3 ]
Grey, Steve [3 ]
Xu, Zhuo [1 ,4 ]
Bar-Ziv, Ezra [4 ]
Vorst, Keith L. [2 ]
Curtzwiler, Greg W. [2 ]
Van Lehn, Reid C. [1 ]
Zavala, Victor M. [1 ]
Huber, George W. [1 ]
机构
[1] Univ Wisconsin Madison, Dept Chem & Biol Engn, Madison, WI 53706 USA
[2] Iowa State Univ, Food Sci & Technol, Polymer & Food Protect Consortium, Ames, IA 50011 USA
[3] Neenah Innovat Ctr, Amcor, Neenah, WI 54956 USA
[4] Michigan Technol Univ, Dept Mech Engn, Houghton, MI 49931 USA
关键词
Recycling; Dissolution; Plastic; Polymer; Economics; Environmental; COSMO-RS; IONIC LIQUIDS; SOLUBILITY; SIMULATION; PLATFORM; DENSITY; WASTE;
D O I
10.1016/j.resconrec.2023.107086
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The recently reported Solvent-Targeted Recovery And Precipitation (STRAP) strategy is used to deconstruct multilayer plastic packaging films into their constituent resins by selective polymer dissolution. To broaden the applicability of STRAP, we demonstrate the process with a flexible post-industrial printed multilayer plastic film used for food packaging. The material was a reverse printed film composed of polyethylene (PE), ethylene vinyl alcohol (EVOH), polyethylene terephthalate (PET), and polyurethane (PU)-based inks. Removal of all colors was observed with biomass-derived gamma-valerolactone (GVL) and the recovered polymers possessed comparable properties to the corresponding virgin resins. A technoeconomic analysis indicates that this STRAP process could be economically feasible at a processing capacity of 6,000 tons per year. Moreover, the production of plastic films with materials recovered by this STRAP process can have a lower climate change impact than the production of films from virgin polymers.
引用
收藏
页数:11
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