Rational design of N-doped porous biomass carbon nanofiber electrodes for flexible asymmetric supercapacitors with high-performance

Flexible supercapacitors have become a concern of flexible energy storage devices. In the process of exploring, the squid ink as N-doped biomass carbon was introduced to self-supporting flexible supercapacitors by elec-trospinning for the first time. By regulating the content of squid ink, the activation temperature, and the mass ratio of KOH-assisted activation, a N-doped porous biomass carbon@polyacrylonitrile (NPBC-1.5@PAN-800-2) with an ideal capacity and an excellent specific surface area (636.68 m2 g-1) was prepared. In addition, ZnO further optimized the capacity (422.7 F/g at 1 A g-1) and as an adhesive-free electrode for flexible asymmetric supercapacitor provided a relatively high specific capacitance, a satisfactory capacitance retention, and a wonderful energy density (48.01 Wh kg- 1 at 1124.43 W kg -1). The capacitance was thought to originate from a suitable microporous structure, N-doped, and metal-derived pseudocapacitance propertie.