Syntheses, crystal structure and properties of two chalcogenidoantimonates Mn(en)3Sb2S4 and Co(en)3Sb2Se4

被引：3

作者：

Zhang, Lirong ^{[1
]}

Li, Na ^{[1
]}

Teri, Gele ^{[1
]}

Shele, Muge ^{[1
]}

Bai, Sagala ^{[1
]}

Baiyin, Menghe ^{[1
]}

机构：

[1] Inner Mongolia Normal Univ, Coll Chem & Environm Sci, Dept Educ Inner Mongolia Autonomous Reg, Key Lab Adv Mat Chem & Devices AMC & DLab, Hohhot 010022, Inner Mongolia, Peoples R China

来源：

POLYHEDRON | 2023年 / 241卷

关键词：

Solvothermal syntheses; Crystal structure; Photoelectric response; Properties; Chalcogenidoantimonates; SOLVOTHERMAL SYNTHESES; FRAMEWORK; CO; PHOTOCURRENT; SULFIDE; CATIONS; SERIES; MN; FE; TM;

D O I：

10.1016/j.poly.2023.116470

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two chalcogenidoantimonates Mn(en)3Sb2S4 (1) and Co(en)3Sb2Se4 (2) have been synthesized in solvothermal conditions. 1 and 2 are consist of transition metal complex cations and [Sb2Q4]2- (Q = S, Se) anions. They have band gaps of 2.20 eV and 2.25 eV, respectively, indicating that they can be used as semiconductor materials. The photocurrent responses of 1 and 2 were also investigated. Photocatalytic experiments showed that both 1 and 2 could degrade methylene blue (MB) upon visible light irradiation, reaching 47 % for 1 and 30 % for 2, indicating that both compounds are good photocatalytic materials. Therefore, they present a promising potential for the photoelectric research chalcogenides.

引用

页数：6

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