Rapid single crystal growth via guest displacement from host-guest complexes

被引:1
|
作者
Horvath, Mikayla L. [1 ]
Jumbelic, Caylee E. [1 ]
Burynski, Rosemarie A. [1 ]
Mistrot, M. Brody [1 ]
Pike, Robert D. [2 ]
Smith, Brian J. [1 ]
Arslan, Hasan [1 ]
机构
[1] Bucknell Univ, Dept Chem, Lewisburg, PA 17837 USA
[2] William & Mary, Dept Chem, Williamsburg, VA 23185 USA
关键词
STATE; CRYSTALLIZATION;
D O I
10.1039/d3cc03406b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The preparation of single crystals of sparingly soluble polycyclic aromatic compounds in MeCN is facilitated by solubilizing ionic host-guest complexation under otherwise poor solvent conditions. The guest is then crystallized within minutes through controlled guest displacement from the host via competitor equilibria, or over days through direct crystallization of the host-guest complex itself.
引用
收藏
页码:11799 / 11802
页数:4
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