Structure and properties of porous glass ceramics from siliceous rocks with the addition of Mg(OH)2

被引:0
|
作者
Rodin, A. I. [1 ]
Ermakov, A. A. [1 ]
Erofeeva, I. V. [1 ]
Erofeev, V. T. [1 ]
机构
[1] Natl Res Mordovia State Univ, Saransk, Mordovia, Russia
来源
MATERIALS PHYSICS AND MECHANICS | 2023年 / 51卷 / 05期
基金
俄罗斯科学基金会;
关键词
glass ceramic; construction material; thermal insulation; siliceous rocks; Mg(OH)2; compressive strength; thermal conductivity; COAL FLY-ASH; MECHANICAL-PROPERTIES; WASTE GLASS; FOAM-GLASS; MICROSTRUCTURE; SLAG; CRYSTALLIZATION; TAILINGS; SYSTEM; FE2O3;
D O I
10.18149/MPM.5152023_13
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Porous glass-ceramic materials are widely used in the construction, reconstruction and repair of objects for various purposes. The article establishes the influence of Mg(OH)2 and together with Al2O3 in the composition of a charge of siliceous rocks and soda ash on the structure and properties of porous glass-ceramic materials. A joint mechanochemical activation of the components was carried out in a planetary ball mill, and then the resulting charge was fired at a maximum temperature of 825 degrees C. The influence of the type and quantity of additives on the structure and properties of porous glass ceramics was established by thermal analysis (TA), X-ray phase analysis (XRD), etc. From the charge with the addition of Mg(OH)2 in glass ceramics, instead of wollastonite, diopside is formed, and instead of devitrite, combeite is formed. The influence of the phase composition of the samples on their properties has been established. The developed porous glass ceramics has an apparent density of 135-235 kg/m3, bending and compressive strength up to 1.6 and 4.2 MPa, respectively, a thermal conductivity coefficient of 0.05-0.067 W/m center dot degrees C, thermal resistance of 170 degrees C, maximum operating temperature up to 870 degrees C, high chemical resistance. The developed materials are superior in many respects to foam glass and other analogues and can be used in the insulation of industrial
引用
收藏
页码:126 / 141
页数:16
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