Cyclodextrins as chiral selectors in capillary electrophoresis: Recent trends in mechanistic studies

被引：32
|
作者：
Chankvetadze, Bezhan [1 ]
Scriba, Gerhard K. E. [1 ,2 ]
机构：
[1] Tbilisi State Univ, Inst Phys & Analyt Chem, Sch Exact & Nat Sci, Tbilisi 0179, Georgia
[2] Friedrich Schiller Univ Jena, Dept Pharmaceut Med Chem, Philosophenweg 14, D-07743 Jena, Germany
来源：
TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 2023年 / 160卷
关键词：
Cyclodextrins; Mass spectroscopy; Microcalorimetry; Molecular modeling; Nuclear magnetic resonance spectroscopy; Recognition mechanisms; NUCLEAR-MAGNETIC-RESONANCE; ENANTIOMER MIGRATION ORDER; BETA-CYCLODEXTRIN; RECOGNITION MECHANISMS; NMR-SPECTROSCOPY; SEPARATION; ENANTIOSEPARATIONS; COMPLEXATION; DERIVATIVES; SELECTIVITY;
D O I：
10.1016/j.trac.2023.116987
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
In the present review the potential of capillary electrophoresis for a better understanding of the fine structural mechanisms of noncovalent interactions and enantioselective intermolecular recognition is highlighted for cyclodextrins and their guests. The importance of applying additional experimental and molecular modeling tools is stressed. The concept is illustrated by results published in the recent liter-ature. The critical opinion of the authors on some current tendencies is provided.(c) 2023 Elsevier B.V. All rights reserved.
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页数：14
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