Halide and Sulfide Electrolytes in Cathode Composites for Sodium All-Solid-State Batteries and their Stability

被引:0
|
作者
Goodwin, Laura E. [1 ,2 ]
Ziegler, Maya [1 ,2 ]
Till, Paul [3 ]
Nazer, Nazia [4 ]
Adelhelm, Philipp [4 ]
Zeier, Wolfgang G. [3 ,5 ]
Richter, Felix H. [1 ,2 ]
Janek, Juergen [1 ,2 ]
机构
[1] Justus Liebig Univ Giessen, Inst Phys Chem, D-35392 Giessen, Germany
[2] Justus Liebig Univ Giessen, Ctr Mat Res ZfM, D-35392 Giessen, Germany
[3] Univ Munster, Inst Inorgan & Analyt Chem, D-48149 Munster, Germany
[4] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
[5] Forschungszentrum Julich, Inst Energie & Klimaforsch IEK, IEK 1 Helmholtz Inst Munster, D-48149 Munster, Germany
关键词
solid electrolyte; sodium battery; all-solid-statebattery; cathode composite; MICROSTRUCTURE;
D O I
10.1021/acsami.4c01652
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Sodium all-solid-state batteries may become a novel storage technology overcoming the safety and energy density issues of (liquid-based) sodium ion batteries at low cost and good resource availability. However, compared to liquid electrolyte cells, contact issues and capacity losses due to interface reactions leading to high cell resistance are still a problem in solid-state batteries. In particular, sulfide-based electrolytes, which show very high ionic conductivity and good malleability, exhibit degradation reactions at the interface with electrode materials and carbon additives. A new group of solid electrolytes, i.e., sodium halides, shows wider potential windows and better stability at typical cathode potentials. A detailed investigation of the interface reactions of Na3SbS4 and Na2.4Er0.4Zr0.6Cl6 as catholytes in cathodes and their cycling performance in full cells is performed. X-ray spectroscopy, time-of-flight spectrometry, and impedance spectroscopy are used to study the interface of each catholyte with a transition metal oxide cathode active material. In addition, impedance measurements were used to study the separator electrolyte Na3SbS4 with the catholyte Na2.4Er0.4Zr0.6Cl6. In conclusion, cathodes with Na2.4Er0.4Zr0.6Cl6 show a higher stability at low C-rates, resulting in lower interfacial resistance and improved cycling performance.
引用
收藏
页码:19792 / 19805
页数:14
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