CTAB-modified peanut husk pre-treated with KMnO4 as an eco-friendly adsorbent for the uptake of Congo red in solution: adsorption and mechanism study

A cationic surfactant (cetyltrimethylammonium bromide, CTAB)-modified peanut husk pretreated with potassium permanganate (KMnO4) was developed and applied as an adsorbent for the removal of Congo red (CR) in aqueous solution. The surface morphology and physicochemical characteristics of the adsorbent labelled as PNK-CTAB were assessed using well-established analytical techniques. The efficiency of PNK-CTAB was assessed via the batch adsorption method using distilled water, tap water and river water as aqueous medium. Results of the batch study showed that the adsorption capacity of PNK-CTAB could reach 70.5 mg g(-1) at 313 K due to its improved surface properties and functionalities. Furthermore, the uptake of CR onto PNK-CTAB was found to be best described by the Elovich model thus suggesting adsorption on a heterogeneous surface, whereas fitting of intraparticle diffusion model indicated the significant role of mass transfer mechanism in the process. The equilibrium data was found to be well described by Langmuir, Temkin and Freundlich models albeit the latter was the best fit. Further analysis of the associated thermodynamics indicated the adsorption process to be endothermic, spontaneous in nature and likely mediated by physisorption processes. The excellent adsorption efficiency of PNK-CTAB toward CR within a wide pH range, negligible influence of some commonly occurring salts, good reusability efficiency, low cost (as confirmed by its cost analysis) and its ability to reduce the cytotoxicity of CR towards human embryonic kidney (HEK) 293 cells suggest the good prospects of this adsorbent for practical applications.