Facile modification of phosphole-based aggregation-induced emission luminogens with sulfonyl isocyanates

被引：7

作者：

Koenig, Nils ^{[1
]}

Godinez-Loyola, Yokari ^{[2
,3
]}

Yang Fangshun ^{[4
]}

Laube, Christian ^{[4
]}

Laue, Michael ^{[5
]}

Loennecke, Peter ^{[1
]}

Strassert, Cristian A. ^{[2
,3
]}

Hey-Hawkins, Evamarie ^{[1
]}

机构：

[1] Univ Leipzig, Inst Inorgan Chem, Fac Chem & Mineral, Johannisallee 29, D-04103 Leipzig, Germany

[2] Westfalische Wilhelms Univ Munster, Inst Anorgan & Analyt Chem, CiMiC, SoN, Heisenbergstr 11, D-48149 Munster, Germany

[3] Westfalische Wilhelms Univ Munster, CeNTech, Heisenbergstr 11, D-48149 Munster, Germany

[4] Leibniz Inst Oberflachenmodifizierung eV, Permoserstr 15, D-04318 Leipzig, Germany

[5] Univ Leipzig, Inst Organ Chem, Fac Chem & Mineral, Johannisallee 29, D-04103 Leipzig, Germany

来源：

CHEMICAL SCIENCE | 2023年 / 14卷 / 09期

关键词：

CARRIER TRANSPORT-PROPERTIES; ELECTRONIC-PROPERTIES; CHEMISTRY; TETRAPHENYLETHENE; AROMATICITY; DERIVATIVES; FABRICATION; COMPLEXES; MOLECULES; CRYSTAL;

D O I：

10.1039/d3sc00308f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphole oxides undergo a highly chemoselective reaction with sulfonyl isocyanates forming sulfonylimino phospholes in high yields. This facile modification proved to be a powerful tool for obtaining new phosphole-based aggregation-induced emission (AIE) luminogens with high fluorescence quantum yields in the solid state. Changing the chemical environment of the phosphorus atom of the phosphole framework results in a significant shift of the fluorescence maximum to longer wavelengths.

引用

页码：2267 / 2274

页数：9

共 50 条

[1] "Irregular" aggregation-induced emission luminogens
Li, Xiaoning
Li, Meng
Yang, Mengqing
Xiao, Huining
Wang, Lidong
Chen, Zhijun
Liu, Shouxin
Li, Jian
Li, Shujun
James, Tony D.
COORDINATION CHEMISTRY REVIEWS, 2020, 418
[2] Wettability with Aggregation-Induced Emission Luminogens
Wang, Zubin
Heng, Liping
Jiang, Lei
MACROMOLECULAR RAPID COMMUNICATIONS, 2017, 38 (18)
[3] Aggregation-Induced Emission of Tetraarylethene Luminogens
Zhao, Zujin
Lam, Jacky W. Y.
Tang, Ben Zhong
CURRENT ORGANIC CHEMISTRY, 2010, 14 (18) : 2109 - 2132
[4] Intracellularly manipulable aggregation of the aggregation-induced emission luminogens
Wang, Wen-Jin
Xin, Zhuo-Yang
Liu, Dan
Liu, Qian
Liu, Yong
Qiu, Zijie
Zhang, Jianquan
Alam, Parvej
Cai, Xu-Min
Zhao, Zheng
Tang, Ben Zhong
Biosensors and Bioelectronics, 2025, 267
[5] Aggregation-induced emission luminogens for RONS sensing
Dai, Jun
Duan, Chong
Huang, Yu
Lou, Xiaoding
Xia, Fan
Wang, Shixuan
JOURNAL OF MATERIALS CHEMISTRY B, 2020, 8 (16) : 3357 - 3370
[6] Mechanochromic Luminescence of Aggregation-Induced Emission Luminogens
Dong, Yong Qiang
Lam, Jacky W. Y.
Tang, Ben Zhong
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (17): : 3429 - 3436
[7] Aggregation-Induced Emission Luminogens for Gas Sensors
Yu, Yongbo
Zhang, Si-Wei
Jiang, Jinhui
Ma, Fulong
Wang, Richard
Huang, Tonghui
Zhao, Jianwei
He, Chao
Wei, Guodan
ADVANCED SENSOR RESEARCH, 2023, 2 (11):
[8] Aggregation-induced emission of dendritic phosphole oxides
Shiraishi, Kentaro
Kashiwabara, Taigo
Sanji, Takanobu
Tanaka, Masato
NEW JOURNAL OF CHEMISTRY, 2009, 33 (08) : 1680 - 1684
[9] Functional Polymeric Micromaterials Based on Aggregation-Induced Emission Luminogens
Chen, Shusheng
Han, Ting
Tang, Ben Zhong
ADVANCED FUNCTIONAL MATERIALS, 2023, 33 (51)
[10] Pyrene-based aggregation-induced emission luminogens and their applications
Islam, Md. Monarul
Hu, Zhen
Wang, Qingsong
Redshaw, Carl
Feng, Xing
MATERIALS CHEMISTRY FRONTIERS, 2019, 3 (05) : 762 - 781

← 1 2 3 4 5 →