The Merger of Halogen Atom Transfer (XAT) and Energy Transfer Catalysis (EnT) for the Modular 1,2-Iminylalkylation of Diazenes

被引：12

作者：

Li, Shan-Shan ^{[1
]}

Jiang, Yu-Shi ^{[1
]}

Chen, Li-Ning ^{[1
]}

Chen, Dan-Na ^{[1
]}

Luo, Xue-Ling ^{[1
]}

Pan, Cheng-Xue ^{[1
]}

Xia, Peng-Ju ^{[1
]}

机构：

[1] Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, Guilin 541004, Peoples R China

来源：

ORGANIC LETTERS | 2023年 / 25卷 / 38期

基金：

中国国家自然科学基金;

关键词：

AZOBENZENES; ALKENES; DIFUNCTIONALIZATION; FUNCTIONALIZATION;

D O I：

10.1021/acs.orglett.3c02584

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 1,2-iminylalkylation of diazenes using alkyl iodides in combination with an O-benzoyl oxime is reported. In this transformation, O-benzoyl oxime acted as a radical precursor and XAT mediator. In addition to common alkyl iodides, other alkyl iodides such as iodomethane, iodomethane-d 3, trifluoroiodomethane, ethyl difluoroiodoacetate, and iodoalkanes containing unprotected hydroxyl and amide groups can also serve as C-radical precursors in the 1,2-iminylalkylation with electrophilic diazenes as radical acceptors.

引用

页码：7009 / 7013

页数：5

共 12 条

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