Synthesis and Optical Properties of Polyaryl 2-(Pyridin-2-yl)phenol-Based Four-Coordinate Organoboron Complexes

被引：12

作者：

Liu, Xiang ^{[1
,2
]}

Zhou, Jinlei ^{[1
,2
]}

Zheng, Huitao ^{[1
,2
]}

Liu, Jiali ^{[1
,2
]}

Liu, Zhihao ^{[1
,2
]}

Ni, Linying ^{[1
,2
]}

Kong, Xiangxi ^{[1
,2
]}

Zhang, Chen ^{[1
,2
,3
]}

Cao, Hua ^{[1
,2
]}

机构：

[1] Guangdong Pharmaceut Univ, Sch Chem & Chem Engn, Zhongshan 528458, Guangdong, Peoples R China

[2] Guangdong Pharmaceut Univ, Guangdong Cosmet Engn & Technol Res Ctr, Zhongshan 528458, Guangdong, Peoples R China

[3] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangzhou 510006, Guangdong, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2023年 / 41卷 / 08期

关键词：

N; O-Bidentate; Indolizines; Organoboron complexes; Cyclopropenones; C-N activation; N-Heterocycles; Cycloaddition; FLUORESCENT BF2 COMPLEXES; HYDROXYLATION; LIGAND; PHOTOOXYGENATION; INDOLIZINES; CATALYSIS;

D O I：

10.1002/cjoc.202200810

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A family of polyaryl 2-(pyridin-2-yl)phenol-based four-coordinate organoboron complexes were prepared in good yields via deconstructive cycloaromatization of indolizines, cyclopropenones, and boric acids. The photoluminescence measurements have revealed that these N,O pi-conjugated tetracoordinate boron complexes display bright fluorescence, large Stokes shifts, and good quantum yields (phi(lum) = 0.15-0.45). In addition, the DFT calculations were carried out to deepen the understanding of the electronic structures and optoelectronic properties of these structurally unprecedented tetracoordinate boron complexes.

引用

页码：924 / 930

页数：7

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