Probing the aromaticity of bis(diazolo)pyrazine radical anions (vol 32, pg 732, 2022)

被引：0
|
作者：
V. Lalov, Andrey [1 ]
Egorov, Mikhail P. [1 ]
Aysin, Rinat R. [2 ]
机构：
[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia
[2] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 01期
关键词：
EXCHANGE; 1,2,5-SELENADIAZOLES;
D O I：
10.1016/j.mencom.2022.11.008
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The aromaticity of a series of heterocyclic radical anions of bis(diazolo)pyrazine type, X(CN)2N2(CN)2Y (X, Y = O, S, Se, Te) was explored by the methods of electron density of delocalized bonds (EDDB) and gauge-included magnetically induced currents (GIMIC). The existence of T-aromaticity that encloses the entire molecule, which was due to delocalization of seven β-electrons, was shown. The degree of aromaticity depends on the nature of the X(Y) heteroatom and varies in the series S > O > Se > Te. © 2022
引用
收藏
页码：141 / 141
页数：1
相关论文
共 50 条
  • [1] Probing the aromaticity of bis(diazolo)pyrazine radical anions
    Lalov, Andrey V.
    Egorov, Mikhail P.
    Aysin, Rinat R.
    MENDELEEV COMMUNICATIONS, 2022, 32 (06) : 732 - 734
  • [2] Special Issues (vol 32, pg 1093, 2022)
    Davison, Robert M.
    Majchrzak, Ann
    Hardin, Andrew
    Ravishankar, Mayasandra-Nagaraja
    INFORMATION SYSTEMS JOURNAL, 2023, 33 (01) : 185 - 185
  • [3] Genetic and phenotypic attributes of splenic marginal zone lymphoma (vol 139, pg 732, 2022)
    Bonfiglio, F.
    Bruscaggin, A.
    Guidetti, F.
    BLOOD, 2023, 141 (13) : 1647 - 1647
  • [4] NASSR Caucus Issue (vol 32, pg 5, 2022)
    Deanna
    EUROPEAN ROMANTIC REVIEW, 2022, 33 (01) : 127 - 127
  • [5] American astronomy: Community, careers and power, 1859-1940 (vol 32, pg 732, 1999)
    Williams, TR
    Lankford, J
    JOURNAL OF SOCIAL HISTORY, 1999, 32 (04) : 1010 - 1010
  • [6] RADICAL IONS .32. ALKYL LIGAND-EXCHANGE IN BIS(CYCLOPENTADIENYL)DIALKYLTITANIUM(III) RADICAL-ANIONS
    KIRA, M
    BOCK, H
    UMINO, H
    SAKURAI, H
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 173 (01) : 39 - 45
  • [7] Young researchers series #3 (vol 32, pg 553, 2022)
    Mukaz, Debora Kamin
    Heyward, Frankie D.
    Eche, Ijeoma Julie
    TRENDS IN CELL BIOLOGY, 2022, 32 (12) : 1049 - 1049
  • [8] Commentaries on "adductive theory construction" (vol 32, pg 194, 2022)
    Kardes
    JOURNAL OF CONSUMER PSYCHOLOGY, 2022, 32 (03) : 548 - 548
  • [9] Barrier Face Coverings for Workers (vol 32, pg 182, 2022)
    Brosseau, L. M.
    Barrier, Stull J.
    NEW SOLUTIONS-A JOURNAL OF ENVIRONMENTAL AND OCCUPATIONAL HEALTH POLICY, 2022,
  • [10] Spins at work: probing charging and discharging of organic radical batteries by electron paramagnetic resonance spectroscopy (vol 15, pg 3275, 2022)
    Kulikov, Ilia
    Panjwani, Naitik A.
    Vereshchagin, Anatoliy A.
    Spallek, Domenik
    Lukyanov, Daniil A.
    Alekseeva, Elena V.
    Levin, Oleg V.
    Behrends, Jan
    ENERGY & ENVIRONMENTAL SCIENCE, 2024, 17 (24) : 9652 - 9652
12345