Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C-O Bond Formation

被引:2
|
作者
Banoun, Camille [1 ]
Magnier, Emmanuel [1 ]
Dagousset, Guillaume [1 ]
机构
[1] Univ Paris Saclay, Inst Lavoisier Versailles, CNRS ,UMR 8180, UVSQ, 45 Ave Etats Unis, F-78000 Versailles, France
关键词
radicals; carbonyloxy; fluoroalkoxy; alkoxy; photoredox catalysis; C-O bonds; ALKOXY RADICALS; ENOL ETHERS; GENERATION; OXIDATION; ALKENES; FUNCTIONALIZATION; CHEMISTRY; ALDEHYDES; METHANOL;
D O I
10.1055/a-2131-4126
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
We report herein recent advances made by our group and others in the field of oxygen-centered radicals generated under photo catalysis. Thanks to the design of new O-radical precursors, these radicals can now be efficiently trapped by unsaturated systems in an intermolecular manner, via the formation of a new C-O bond.
引用
收藏
页码:268 / 278
页数:11
相关论文
共 50 条
  • [1] C-H Bond Activation by Oxygen-Centered Radicals over Atomic Clusters
    Ding, Xun-Lei
    Wu, Xiao-Nan
    Zhao, Yan-Xia
    He, Sheng-Gui
    ACCOUNTS OF CHEMICAL RESEARCH, 2012, 45 (03) : 382 - 390
  • [2] Intermolecular C-O Bond Formation with Alkoxyl Radicals: Photoredox-Catalyzed α-Alkoxylation of Carbonyl Compounds
    Banoun, Camille
    Bourdreux, Flavien
    Magnier, Emmanuel
    Dagousset, Guillaume
    ORGANIC LETTERS, 2021, 23 (22) : 8926 - 8930
  • [3] C-O BOND FORMATION BY DIRECT ADDITION OF METHYL RADICALS TO SURFACE OXYGEN ON RH(111)
    BOL, CWJ
    FRIEND, CM
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (30) : 8053 - 8054
  • [4] Selectivity in the chemistry of oxygen-centered radicals - The formation of carbon-oxygen bonds
    Hartung, J
    Gottwald, T
    Spehar, K
    SYNTHESIS-STUTTGART, 2002, (11): : 1469 - 1498
  • [5] Cross-dehydrogenative coupling for the intermolecular C-O bond formation
    Krylov, Igor B.
    Vil', Vera A.
    Terent'ev, Alexander O.
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2015, 11 : 92 - 146
  • [6] Mechanical Insights into Activation of Peroxides by Quinones: Formation of Oxygen-Centered Radicals or Singlet Oxygen
    Gu, Jia
    Song, Yang
    Yang, Yi
    Guan, Chaoting
    Jiang, Jin
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2022, 56 (12) : 8776 - 8783
  • [7] Mechanical Insights into Activation of Peroxides by Quinones: Formation of Oxygen-Centered Radicals or Singlet Oxygen
    Gu, Jia
    Song, Yang
    Yang, Yi
    Guan, Chaoting
    Jiang, Jin
    Environmental Science and Technology, 2022, 56 (12): : 8776 - 8783
  • [8] Use of tunable ligands allows for intermolecular Pd-catalyzed C-O bond formation
    Vorogushin, AV
    Huang, XH
    Buchwald, SL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (22) : 8146 - 8149
  • [9] Peroxide electrophiles for C-O bond formation
    Horn, Alissa
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 249
  • [10] C-O bond formation by polyketide synthases
    Kwon, HJ
    Smith, WC
    Scharon, AJ
    Hwang, SH
    Kurth, MJ
    Shen, B
    SCIENCE, 2002, 297 (5585) : 1327 - 1330