Application of X-rays to interpret alloying effects on the 3d and 4s4p electron populations of nickel-boron-nitrogen metal matrix composites

被引:0
|
作者
Koksal, O. K. [1 ,2 ]
机构
[1] Adiyaman Univ, Fac Engn, Dept Elect Elect Engn, TR-02040 Adiyaman, Turkiye
[2] Karadeniz Tech Univ, Fac Sci, Dept Phys, TR-61080 Trabzon, Turkiye
关键词
Ni-B-N; metal matrix composites; coating materials; 3d and 4s4p electron; K-beta/K-alpha intensity ratio; ALPHA INTENSITY RATIOS; SHELL FLUORESCENCE PARAMETERS; CHARGE-TRANSFER; HEAT-TREATMENT; NI; ZN; CU; CRXNI1-X; COATINGS; DELOCALIZATION;
D O I
10.1139/cjp-2022-0336
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
For this experiment, nickel-boron and nickel-boron-nitrogen alloys are created using the electrochemical depositionmethod. Utilizing energy-dispersive X-ray methods, the nickel-boron and nickel-boron-nitrogen alloys are characterized. X-ray diffraction was used to examine the crystal structure of nickel-boron and nickel-boron-nitrogen alloys. An energy dispersed X-ray fluorescence spectrometer is used to gather X-ray photons from the present samples. The number of radiated X-ray photons from the present specimens is used to compute the K-beta/K(alpha)a intensity ratios. The theoretical Coulomb and Babushkin gauges are used to calculate the populations of the 3d and 4s4p electrons. The observed data imply that shielding effects from 4s3d orbitals, hybridization, changes in energy levels, and charge transfer mechanism may be the causes of the variance in 3d and 4s4p electron populations. In an effort to clarify the conclusions drawn as a result of all these computations, this study contrasts the results with those of pure nickel.
引用
收藏
页码:420 / 427
页数:8
相关论文
共 3 条
  • [1] Precision spectroscopy of Kaonic helium-3 and helium-4 3d → 2p X-rays
    Ishiwatari, T.
    Bazzi, M.
    Bhang, H.
    Beer, G.
    Bombelli, L.
    Bragadireanu, A. M.
    Cargnelli, M.
    Choi, S.
    Corradi, G.
    Curceanu , C.
    d'Uffizi, A.
    Enomoto, S.
    Fiorini, C.
    Frizzi, T.
    Fujioka, H.
    Fujiwara, Y.
    Ghio, F.
    Girolami, B.
    Guaraldo, C.
    Hashimoto, T.
    Hayano, R. S.
    Hiraiwa, T.
    Iio, M.
    Iliescu, M.
    Ishimoto, S.
    Itahashi, K.
    Iwasaki, M.
    Kienle, P.
    Kou, H.
    Sandri, P. Levi
    Longoni, A.
    Lucherini, V.
    Marton, J.
    Matsuda, Y.
    Noumi, H.
    Ohnishi, H.
    Okada, S.
    Outa, H.
    Pietreanu, D.
    Ponta, T.
    Rizzo, A.
    Vidal, A. Romero
    Sakuma, F.
    Sato, M.
    Scordo, A.
    Sekimoto, M.
    Shi, H.
    Sirghi, D. L.
    Sirghi, F.
    Suzuki, T.
    HADRON 2009, 2010, 1257 : 765 - +
  • [2] Polarization of the nf → 3d (n=4, 5, 6) x-rays from tungsten ions following electron-impact excitation and dielectronic recombination processes
    Xie, L. Y.
    Ma, X. Y.
    Dong, C. Z.
    Wu, Z. W.
    Shi, Y. L.
    Jiang, J.
    JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER, 2014, 141 : 31 - 39
  • [3] NEW APPROACH FOR MANUFACTURING Ti-6Al-4V+40%TiC METAL-MATRIX COMPOSITES BY 3D PRINTING USING CONIC ELECTRON BEAM AND CORED WIRE. PT. 1: MAIN FEATURES OF THE PROCESS, MICROSTRUCTURE FORMATION AND BASIC CHARACTERISTICS OF 3D PRINTED MATERIAL
    Markovsky, P. E.
    Kovalchuk, D. V.
    Akhonin, S. V.
    Schwab, S. L.
    Savvakin, D. G.
    Stasiuk, O. O.
    Oryshych, D. V.
    Vedel, D. V.
    Skoryk, M. A.
    Tkachuk, V. P.
    USPEKHI FIZIKI METALLOV-PROGRESS IN PHYSICS OF METALS, 2023, 24 (04): : 715 - 740