Innovative methodology for comprehensive utilization of refractory low-grade iron ores

被引:8
|
作者
Liang, Zhikai [1 ]
Peng, Xin [1 ]
Huang, Zhucheng [2 ]
Li, Jiayuan [1 ]
Yi, Lingyun [2 ]
Huang, Boyang [3 ]
Chen, Changzhong [1 ]
机构
[1] Xiangnan Univ, Sch Chem & Environm Sci, Hunan Prov Key Lab Xiangnan Rare Precious Met Cpds, Chenzhou 423000, Peoples R China
[2] Cent South Univ, Sch Minerals Proc & Bioengn, Changsha 410083, Hunan, Peoples R China
[3] Nanyang Technol Univ, Singapore Ctr 3D Printing, Sch Mech Aerosp & Engn, Singapore, Singapore
关键词
High-silica iron ores; Synchronous conversion; In-situ dissection; Direct reduced iron (DRI) powder; Precipitated amorphous silica; GREEN METALLURGICAL TECHNIQUE; CARBON COMPOSITE PELLETS; STICKING MECHANISM; REACTION-KINETICS; VOLATILE MATTER; COAL COMPOSITE; GOETHITE ORE; ROTARY KILN; REDUCTION; SILICA;
D O I
10.1016/j.powtec.2023.118283
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The sustainable future of the steel industry crucially depends on the development of economical and environ-mentally responsible technologies to produce low-impurity iron powder from low-grade iron ores. Here, we developed an innovative process with low CO2 emission and energy consumption to comprehensively utilize high-silica low-iron ores from refractory waste. An excellent direct reduced iron powder containing 0.50% silica was obtained under optimum conditions with an iron recovery of 91.75%. Concomitantly, an excellent leach solution with high Si concentration and low impurities was obtained, which was appropriate to be processed into precipitated amorphous silica. The mechanism analysis revealed NaCl is involved in greatly reducing the theoretical formation temperature of metallic iron and significantly promoting the conversion of silicon minerals, thus facilitating the formation of the excellent DRI and leach solution. These findings highlight effectiveness of this novel approach in handling high-silica iron ores, eventually contributing to future sustainability of steel industry.
引用
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页数:22
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