Sodium hydroxide or tetramethylammonium hydroxide modified corncob combined with biodegradable polymers to prepare slow-release carbon source for wastewater denitrification

This study proposed a method to improve the bioavailability of artificially prepared carbon sources for the purpose of wastewater denitrification. This carbon source (named SPC) was prepared by mixing corncobs with poly(3-hydroxybutyrate-3-hydroxyvalerate) (PHBV), where the corncobs were pretreated by NaOH or TMAOH. The results of compositional analysis and FTIR showed that both NaOH and TMAOH degraded lignin, hemi-cellulose and their connection bonds in corncob, thus increased the cellulose content from 39% to 53% and 55%, respectively. The cumulative carbon release from SPC was about 9.3 mg/g and was consistent with both the first -order kinetic and Ritger-Peppas equation. The released organic matters contained low concentration of refractory components. Correspondingly, it showed excellent denitrification performance in simulated wastewater, and the total nitrogen (TN) removal rate was above 95% (influent NO3 -N was 40 mg/L) and effluent residual chemical oxygen demand (COD) was less than 50 mg/L.