Decarbonization of the chemical industry through electrification: Barriers and opportunities

被引:127
|
作者
Mallapragada, Dharik S. [1 ]
Dvorkin, Yury [2 ]
Modestion, Miguel A. [3 ]
V. Esposito, Daniel [4 ,6 ]
Smith, Wilson A. [5 ,6 ,7 ]
Hodge, Bri-Mathia [7 ,8 ]
Harold, Michael P. [9 ]
Donnelly, Vincent M. [9 ]
Nuz, Alic [10 ]
Bloomquist, Casey [3 ]
Baker, Kyri [11 ]
Grabow, Lars C. [9 ,12 ]
Yan, Yushan [13 ]
Rajput, Nav Nidhi [14 ]
Hartman, Ryan L. [3 ]
Biddinger, Elizabeth J. [15 ]
Aydil, Eray S. [3 ]
Taylor, Andre D. [3 ]
机构
[1] MIT, MIT Energy Initiat, Cambridge, MA 02139 USA
[2] Johns Hopkins Univ, Ralph OConnor Sustainable Energy Inst, Dept Elect & Comp Engn, Dept Civil & Syst Engn, Baltimore, MD 21210 USA
[3] NYU, Dept Chem & Biomol Engn, Tandon Sch Engn, Brooklyn, NY 11201 USA
[4] Columbia Univ City New York, Columbia Electrochem Energy Ctr, Lenfest Ctr Sustainable Energy, Dept Chem Engn, 500 W 120th St, New York, NY 10027 USA
[5] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80303 USA
[6] Natl Renewable Energy Lab, 15013 Denver W Pkwy, Golden, CO USA
[7] Univ Colorado, Renewable & Sustainable Energy Inst RASEI, 4001 Discovery Dr, Boulder, CO 80303 USA
[8] Univ Colorado Boulder, Elect Comp & Energy Engn ECEE Dept, 425 UCB, Boulder, CO 80309 USA
[9] Univ Houston, William A Brookshire Dept Chem & Biomol Engn, Houston, TX 77204 USA
[10] NYU, Tandon Sch Engn, Dept Elect & Comp Engn, Brooklyn, NY 11201 USA
[11] Univ Boulder, Dept Civil Architectural & Engn, Boulder, CO USA
[12] Texas Ctr Superconduct Houston TcSUH, Houston, TX 77204 USA
[13] Univ Delaware, Ctr Catalyt Sci & Technol, Dept Chem & Biomol Engn, Newark, DE 19716 USA
[14] SUNY Stony Brook, Dept Mat Sci & Chem Engn, Stony Brook, NY USA
[15] CUNY, Dept Chem Engn, City New York, New York, NY USA
关键词
AMMONIA-SYNTHESIS; ENERGY-STORAGE; HYDROGEN; GAS; REDUCTION; LIQUIDS; COST; CO2;
D O I
10.1016/j.joule.2022.12.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The chemical industry is a major source of economic productivity and employment globally and among the top 3 industrial sources of greenhouse gas (GHG) emissions, along with steel and cement. As global demand for chemical products continues to grow, there is an urgency to develop and deploy sustainable chemical produc-tion pathways and to reconsider continued investment in current emission-intensive production technologies. This perspective de-scribes the challenges and opportunities to decarbonize the chemi-cal industry via electrification powered by low-carbon electricity supply, both in the near term and long term, and it discusses four technological pathways ranging from the more mature direct substi-tution of heat with electricity and use of hydrogen to technologically less mature, yet potentially more selective, approaches based on electrochemistry and plasma. Finally, we highlight the key elements of integrating an electrified industrial process with the power sector to leverage process flexibility to reduce energy costs of chemical production and provide valuable power grid support services. Un-locking such plant-to-grid coordination and the four electrification pathways has significant potential to facilitate rapid and deep de-carbonization of the chemical industry sector.
引用
收藏
页码:23 / 41
页数:19
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