Using Highly Flexible SbSn@NC Nanofibers as Binderless Anodes for Sodium-Ion Batteries

Flexible and binderless electrodes have become a promising candidate for the next generation of flexible power storage devices. However, developing high-performance electrode materials with high energy density and a long cycle life remains a serious challenge for sodium-ion batteries (SIBs). The main issue is the large volume change in electrode materials during the cycling processes, leading to rapid capacity decay for SIBs. In this study, flexible electrodes for a SnSb alloy-carbon nanofiber (SnSb@NC) membrane were successfully synthesized with the aid of hydrothermal, electrospinning and annealing processes. The as-prepared binderless SnSb@NC flexible anodes were investigated for the storage properties of SIBs at 500 & DEG;C, 600 & DEG;C and 700 & DEG;C (SnSb@NC-500, SnSb@NC-600 and SnSb@NC-700), respectively. And the flexible SnSb@NC-700 electrode displayed the preferable SIB performances, achieving 240 mAh/g after 100 cycles at 0.1 A g-1. In degree-dependent I-V curve measurements, the SnSb@NC-700 membrane exhibited almost the same current at different bending degrees of 0 & DEG;, 45 & DEG;, 90 & DEG;, 120 & DEG; and 175 & DEG;, indicating the outstanding mechanical properties of the flexible binderless electrodes.