Experimental investigation of hydrogen-intensified synthetic natural gas production via biomass gasification: a technical comparison of different production pathways

A sustainable and secure energy supply requires alternative concepts for energy generation. Utilizing biomass to produce synthetic natural gas (SNG) allows the synthesis of a currently widely used energy carrier on a renewable basis. The additional integration of hydrogen increases the carbon utilization of the biomass. This study experimentally investigates and compares the production of raw-SNG in three novel process chain configurations combining the advanced dual fluidized bed (DFB) gasification technology, gas cleaning units, and a fluidized bed methanation reactor. The three process chains comprise the direct methanation of DFB product gas, a hybrid route with hydrogen addition to the DFB product gas, and the methanation of a hydrogen-enriched product gas generated through DFB gasification with in situ CO2 removal (SER process). The direct methanation of the DFB product gas yielded a raw-SNG CH4 content of 40 vol.-%(db) at 360 degrees C and atmospheric pressure conditions. Through the integration of external hydrogen in a hybrid process, the carbon utilization of the biomass could be increased from 37% to around 70% at an unchanged cold gas efficiency of 58-59%. Via the SER process, a high raw-SNG CH4 content of 70 vol.-%(db) was achieved at an increased cold gas efficiency of 66% without the need for external hydrogen. Finally, a comparison points out the main advantages of the process configurations and provides a decision basis for novel SNG production pathways.