Preparation of photoluminescent nanocomposite by one-step method from cobalt oxide-Jeffamine based on novel polymer dot as a high-performance and ultra-stable symmetric supercapacitor

被引:3
|
作者
Alimola, Fariba [1 ]
Arsalani, Nasser [1 ]
Ahadzadeh, Iraj [2 ]
机构
[1] Univ Tabriz, Fac Chem, Dept Organ & Biochem, Res Lab Polymer, POB 51666, Tabriz, Iran
[2] Univ Tabriz, Fac Chem, Res Lab Electrochem Instrumentat & Energy Syst, Dept Phys Chem, POB 51666, Tabriz, Iran
关键词
Nanocomposite; Polymer dot; Supercapacitor; Photoluminescence; Jeffamine; GRAPHENE QUANTUM DOTS; CO3O4;
D O I
10.1016/j.jallcom.2023.169851
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Polymer dots are a new class of quantum dots that have attracted much attention from researchers. Based on, in this work, for the first time, using a one-step method, the new PDJA-Co3O4 nanocomposite with a quantum yield of 65.45%, based on the polymer dot of jeffamine was synthesized, which has ideal super-capacitor properties. The new polymer dot-based Jeffamine (PDJA) was first synthesized using a Jeffamine polymer and simultaneously composited with cobalt oxide by the solvothermal method. The photo-luminescence properties and supercapacitor performance of the PDJA-Co3O4 nanocomposite and the PDJA were investigated. The PDJA-Co3O4 nanocomposite and the PDJA were prepared as electrode materials, and analysis of CV, GCD, and EIS was performed that the specific capacitance of the PDJA-Co3O4 nanocomposite electrode material and the PDJA electrode material are 978 F.g-1 and 283 F.g-1 at 50 mV/s, respectively. Also, the PDJA-Co3O4 nanocomposite and the PDJA have cyclic stability of 98.37% and 91.57% up to 10,000 cycles of cyclic voltammetry at 100 mV/s, respectively. Then, two symmetric supercapacitors were manufactured of the PDJA-Co3O4 nanocomposite and the PDJA. Finally, due to the high conductivity of the PDJA-Co3O4 na-nocomposite active material, the symmetric supercapacitor of PDJA-Co3O4 nanocomposite turned on the LED lamp.(c) 2023 Published by Elsevier B.V.
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页数:12
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