Synthesis and Structure of Trisubstituted closo-Decaborane [B10H7(1-IPh)(6(7),10-NHOCCH3)]: Specifics of Interaction between the [2-B10H9NH=C(OH)CH3]- Ion and PhI(OAc)2

被引：2
|
作者：
Voinova, V. V. [1 ]
Selivanov, N. A. [1 ]
Bykov, A. Yu. [1 ]
Kubasov, A. S. [1 ]
Zhdanov, A. P. [1 ]
Zhizhin, K. Yu. [1 ]
Kuznetsov, N. T. [1 ]
机构：
[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2023年 / 68卷 / 06期
关键词：
closo-decaborate anion; boroxazole; iodonium derivative; NUCLEOPHILIC-ADDITION; DERIVATIVES; ANION;
D O I：
10.1134/S003602362360017X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The preparation of trisubstituted closo-decaboranes by reacting 1,2-boroxazoles with PhI(OAc) 2 was studied. The process could be implemented in a one-pot variant proceeding from borylated iminol. The reaction products were characterized by H-1, B-11, and C-13 NMR spectroscopy. The XRD structure of the compound [B10H7(1-IPh)(6,10-NHOCCH3)] was determined.
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收藏
页码：678 / 683
页数：6
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